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Catena-Poly[[diazido-manganese(II)]bis-[μ-1-(4-pyridylmeth-yl)-1H-benzimidazole]].

ABSTRACT: In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (-)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (-) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C-H⋯N hydrogen bonds.

SUBMITTER: Liu CS

PROVIDER: S-EPMC2914919 | biostudies-literature |

REPOSITORIES: biostudies-literature

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catena-Poly[[[diiodidocadmium(II)]-?-1-(4-pyridylmeth-yl)-1H-benzimidazole] methanol hemisolvate].

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catena-Poly[[[diaqua-diformatonickel(II)]-μ-1,4-bis-(1H-benzimidazol-1-yl)benzene] dihydrate].

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catena-Poly[[chloridocadmium(II)]bis-{μ-1-[(2-ethyl-1H-imidazol-1-yl)meth-yl]-1H-benzotriazole}[chloridocadmium(II)]di-μ-chlorido].

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| S-EPMC2980034 | biostudies-literature

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Project description:The title complex, [Mn(N(3))(2)(C(9)H(10)N(2)O)(2)], possesses crystallographically imposed twofold symmetry. The Mn(II) atom is coordinated by four N atoms and two O atoms in a distorted octa-hedral geometry. The crystal packing is stabilized by strong inter-molecular O-H⋯N hydrogen bonds.

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