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Catena-Poly[[diazido-manganese(II)]bis-[μ-1-(4-pyridylmeth-yl)-1H-benzimidazole]].

ABSTRACT: In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (-)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (-) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C-H⋯N hydrogen bonds.

SUBMITTER: Liu CS

PROVIDER: S-EPMC2914919 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[diazido-manganese(II)]bis-[μ-1-(4-pyridylmeth-yl)-1H-benzimidazole]].

Liu Chun-Sen CS Wang Jun-Jie JJ Yan Li-Fen LF

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (-)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (-) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network paralle ...[more]

PMID: 21200603

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