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Tetra-kis(N,N-diethyl-carbamato)titanium(IV).

ABSTRACT: The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.

SUBMITTER: Straessler NA

PROVIDER: S-EPMC2914932 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Tetra-kis(N,N-diethyl-carbamato)titanium(IV).

Straessler Nicholas A NA Caudle M Tyler MT Groy Thomas L TL

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36. ...[more]

PMID: 21200619

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