Browse
Submit Data
Databases
API
Help

Dataset Information

16 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N-[4-(Dimethyl-amino)benzyl-idene]-4-ethoxy-aniline.

ABSTRACT: In the title compound, C(17)H(20)N(2)O, the mol-ecular core is planar, with a central C-N=C-C torsion angle of -179.3 (3)°. However, the overall geometry is not planar, with a dihedral angle of 61.96 (1)° between the two benzene rings, which adopt a trans configuration with respect to the C=N bond [1.269 (4) Å]. The bond lengths and angles are within normal ranges.

SUBMITTER: Wang Q

PROVIDER: S-EPMC2915009 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

2-Chloro-N-[4-(dimethyl-amino)benzyl-idene]aniline.

Project description:In the title mol-ecule, C(15)H(15)ClN(2), the dihedral angle between the aromatic is 64.1 (2)°.

| S-EPMC2960011 | biostudies-literature

N-[(E)-4-Chloro-benzyl-idene]-2,4-dimethyl-aniline.

Project description:The title mol-ecule, C(15)H(14)ClN, exists in a trans configuration with respect to the C=N bond [1.2813?(16)?Å]. The dihedral angle between the benzene rings is 52.91?(6)°. The crystal structure is stabilized by weak inter-molecular C-H?? inter-actions.

| S-EPMC3212319 | biostudies-literature

2,3-Dimethyl-N-[(E)-4-nitro-benzyl-idene]aniline.

Project description:In the title compound, C(15)H(14)N(2)O(2), the aromatic rings are oriented at a dihedral angle of 24.52?(5)°. The dihedral angle between the nitro group and its parent benzene ring is 9.22?(16)°. In the crystal, mol-ecules inter-act through aromatic ?-? stacking inter-actions [centroid-centroid separations = 3.8158?(14) and 3.9139?(14)?Å].

| S-EPMC3006706 | biostudies-literature

N-[(E)-4-Chloro-benzyl-idene]-2,3-dimethyl-aniline.

Project description:In the title compound, C(15)H(14)ClN, the conformation about the C=N bond is trans and the dihedral angle between the aromatic rings is 51.48 (4)°. In the crystal, some very weak C-H⋯π inter-actions may help to establish the packing.

| S-EPMC3007017 | biostudies-literature

2,3-Dimethyl-N-[(E)-2,4,5-trimeth-oxy-benzyl-idene]aniline.

Project description:In the title compound, C(18)H(21)NO(3), the C=N bond has a trans conformation and the benzene rings are oriented at a dihedral angle of 61.32?(6)°. The C atoms of the three meth-oxy groups are all roughly coplanar with their attached ring [deviations = 0.219?(2), -0.097?(2) and -0.137?(2)?Å]. In the crystal, a weak C-H?? inter-action may help to establish the packing.

| S-EPMC3007282 | biostudies-literature

4-Chloro-N-[4-(diethyl-amino)benzyl-idene]aniline.

Project description:The asymmetric unit of the title compound, C(17)H(19)ClN(2), contains two independent mol-ecules which differ by a 180° flip in the orientation of the 4-chloro-aniline unit with respect to the diethyl-amino-benzyl-idene unit [N=C-C-C = 10.0?(3) and -170.6?(2)°]. The dihedral angles between the two aromatic rings are 64.0?(1) and 66.5?(1)° in the two independent mol-ecules.

| S-EPMC2979698 | biostudies-literature

4-Bromo-N-[4-(diethyl-amino)-benzyl-idene]aniline.

Project description:The asymmetric unit of the title compound, C(17)H(19)BrN(2), contains two independent mol-ecules. The dihedral angles between the two benzene rings in are 60.4 (2) and 61.0 (2)°.

| S-EPMC3008128 | biostudies-literature

N'-[4-(Dimethyl-amino)benzyl-idene]benzohydrazide.

Project description:In the title mol-ecule, C(16)H(17)N(3)O, the two aromatic rings form a dihedral angle of 4.51?(18)°. In the crystal structure, inter-molecular N-H?O hydrogen bonds link mol-ecules related by translation along the a axis into ribbons.

| S-EPMC2970421 | biostudies-literature

N'-[4-(Dimethyl-amino)benzyl-idene]acetohydrazide.

Project description:The title compound, C(11)H(15)N(3)O, crystallizes with two independent mol-ecules per asymmetric unit which differ slightly in their side-chain orientations: the C=N-N-C torsion angle is -176.2 (3)° in one of the mol-ecules and -179.83 (3)° in the other. Each independent mol-ecule adopts a trans configuration with respect to the C=N bond. The two independent mol-ecules are related by a pseudo-inversion center and they exist as a N-H⋯O hydrogen-bonded dimer. The dimers are linked into zigzag chains along [100] by C-H⋯O hydrogen bonds.

| S-EPMC2969918 | biostudies-literature

2-Benzyl-sulfanyl-N-(1,3-dimethyl-imidazolidin-2-yl-idene)aniline.

Project description:The mol-ecular structure of the title compound, C18H21N3S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N-C-C-S torsion angle of -5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the asscociated C-N-C angle is 125.71 (10)°. The guanidine-like C=N double bond is clearly localized, with a bond length of 1.2879 (14) Å. The C-S-C angle is 102.12 (5)° and the S-C(aromatic) and S-C bond lengths are 1.7643 (11) and 1.8159 (12) Å.

| S-EPMC3629606 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data