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Tetra-kis(?-propanoato-?O:O')bis-[(1,10-phenanthroline-?N,N')(propanoato-?O,O')samarium(III)].

ABSTRACT: The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric mol-ecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502?(2)?Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroline ligand and seven carboxylate O atoms from five propanoate anions, to form a distorted tricapped trigonal prism.

SUBMITTER: Wang CX

PROVIDER: S-EPMC2915056 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Tetra-kis(μ-propanoato-κO:O')bis-[(1,10-phenanthroline-κN,N')(propanoato-κO,O')samarium(III)].

Wang Chun-Xiang CX Li Zhi-Feng ZF Xiong Shu-Hua SH Wang Ping P

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The title complex, [Sm(2)(C(3)H(5)O(2))(6)(C(12)H(8)N(2))(2)], is a dinuclear centrosymmetric mol-ecule, in which two crystallographically equivalent Sm atoms, separated by 3.9502 (2) Å, are bridged by four propanoate anions. Each Sm atom is coordinated by two N atoms from one chelating phenanthroline ligand and seven carboxylate O atoms from five propanoate anions, to form a distorted tricapped trigonal prism. ...[more]

PMID: 21200461

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