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Catena-Poly[[[diaqua-iron(II)]-?-pyrazine-2,3-dicarboxyl-ato] dihydrate].


ABSTRACT: The crystal structure of the title compound, {[Fe(C(6)H(2)N(2)O(4))(H(2)O)(2)]·2H(2)O}(n), was synthesized by a diffusion method. It has a one-dimensional polymeric chain structure and the chains are further connected into a three-dimensional structure by hydrogen bonds. The Fe(II) ion has a distorted octa-hedral coordination environment, with two N and two O atoms from the pyrazine-2,3-dicarboxyl-ate ligands in the equatorial plane and with two water mol-ecules in axial positions. The Fe atom lies on a crystallographic centre of symmetry and a twofold rotation axis passes through the pyrazine ring.

SUBMITTER: Xu H 

PROVIDER: S-EPMC2915058 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[[diaqua-iron(II)]-μ-pyrazine-2,3-dicarboxyl-ato] dihydrate].

Xu Haiyun H   Ma Huailing H   Xu Maotian M   Zhao Wenxian W   Guo Baoguo B  

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1


The crystal structure of the title compound, {[Fe(C(6)H(2)N(2)O(4))(H(2)O)(2)]·2H(2)O}(n), was synthesized by a diffusion method. It has a one-dimensional polymeric chain structure and the chains are further connected into a three-dimensional structure by hydrogen bonds. The Fe(II) ion has a distorted octa-hedral coordination environment, with two N and two O atoms from the pyrazine-2,3-dicarboxyl-ate ligands in the equatorial plane and with two water mol-ecules in axial positions. The Fe atom l  ...[more]

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