Unknown

Dataset Information

0

A one-dimensional ladder-like coordination polymer: poly[[hexa-aqua-bis(?-5-nitro-benzene-1,3-dicarboxyl-ato-?O,O',O'')(?-oxalato-?O,O':O'',O''')diyttrium(III)] trihydrate].

ABSTRACT: In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitro-benzene-1,3-dicarboxyl-ate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water mol-ecules coordinate to the Y(III) ion to complete an eight-coordinate distorted dodecahedral geometry. The ladder-like polymers are assembled together by hydrogen bonding and ?-? stacking [centrio-centriod distance = 3.819?(9)?Å] in the crystal structure.

SUBMITTER: Fu Z 

PROVIDER: S-EPMC2915072 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

A one-dimensional ladder-like coordination polymer: poly[[hexa-aqua-bis(μ-5-nitro-benzene-1,3-dicarboxyl-ato-κO,O',O'')(μ-oxalato-κO,O':O'',O''')diyttrium(III)] trihydrate].

Fu Zhong Z   Lin Ying Y   Zhou Yun-You YY   Zhang Hong-Tao HT  

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the crystal structure of the title one-dimensional coordination polymer, [Y(2)(C(8)H(3)NO(6))(2)(C(2)O(4))(H(2)O)(6)]·3H(2)O, each Y(III) ion is bridged to its neighbours by two 5-nitro-benzene-1,3-dicarboxyl-ate (nbdc) dianions and one oxalate dianion (located on an inversion centre) to form a ladder-like polymeric structure. The two carboxylate groups of nbdc assume different modes of coordination, one is chelating whereas the other is monodentate. Three water mol-ecules coordinate to the Y  ...[more]

Similar Datasets

Unknown Tetra-aqua-hexa-kis(?(2)-quinoline-4-carboxyl-ato)diyttrium(III) dihydrate.
| S-EPMC2960038 | biostudies-literature
Unknown Poly[hexa-aqua-hexa-kis-(?-pyridine-2,4-dicarboxyl-ato)tricopper(II)dieuropium(III)].
| S-EPMC3011568 | biostudies-literature
Unknown Poly[aqua-bis(?-benzene-1,2-dicarboxyl-ato)ethano-ltetra-lithium].
| S-EPMC2968522 | biostudies-literature
Unknown Poly[hexa-aqua-bis-(?(4)-pyrimidine-4,6-dicarboxyl-ato)tetra-lithium].
| S-EPMC3470151 | biostudies-literature
Unknown Poly[[hexa-aqua-bis-(?3-pyrimidine-4,6-dicarboxyl-ato)dicalcium] dihydrate].
| S-EPMC3588738 | biostudies-literature
Unknown Poly[tris-(?-2-amino-benzene-1,4-dicarboxyl-ato)tetra-kis-(N,N-dimethyl-formamide)-diyttrium(III)].
| S-EPMC3050248 | biostudies-literature
Unknown Poly[[aqua-tris-(?(4)-benzene-1,2-dicarboxyl-ato)dilanthanum(III)] hemihydrate].
| S-EPMC3201334 | biostudies-literature
Unknown catena-Poly[[aqua-(imidazole)-cadmium(II)]-?(3)-benzene-1,3-dicarboxyl-ato].
| S-EPMC3006711 | biostudies-literature
Unknown Poly[[hexa-aqua-(?(2)-oxalato-?O,O:O,O)bis(?(3)-pyridine-2,4-dicarboxyl-ato-?N,O:O:O)dicerium(III)] monohydrate].
| S-EPMC3254299 | biostudies-literature
Unknown Poly[[hexa-aqua-(?(2)-oxalato-?O,O:O,O)bis-(?(3)-pyridine-2,4-dicarboxyl-ato-?N,O:O:O)dilanthanum(III)] monohydrate].
| S-EPMC3238643 | biostudies-literature