Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

{1-[1-(3-Carboxy-propanamido)eth-yl]-1',2-bis-(diphenyl-phosphino)ferrocene-?P,P'}dichloridoplatinum(II) dichloro-methane 1.25-solvate.

ABSTRACT: The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4?(2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H?O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H?Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.

SUBMITTER: Spencer LC

PROVIDER: S-EPMC2915101 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

{1-[1-(3-Carboxy-propanamido)eth-yl]-1',2-bis-(diphenyl-phosphino)ferrocene-κP,P'}dichloridoplatinum(II) dichloro-methane 1.25-solvate.

Spencer Lara C LC Bjelosevic Haris H Darkwa James J Elmroth Sofi K C SK Persson Tina T

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H⋯O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has ...[more]

PMID: 21200513

Similar Datasets

[?-1,1'-Bis(diphenyl-phosphino)ferrocene]bis-{[(Z)-O-ethyl N-phenyl-thio-carbamato-?S]gold(I)} dichloro-methane solvate.

Project description:The binuclear title compound, [Au(2)Fe(C(9)H(10)NOS)(2)(C(17)H(14)P)(2)]·CH(2)Cl(2), which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1:1 dichloro-methane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1-Au-P1 angle is 175.35?(5) °] which is due to an intra-molecular Au?O contact [3.080?(5)?Å]. The primary inter-molecular contacts between binuclear mol-ecules are of the type C-H??, and are arranged so as to form columns in the a-axis direction in which the disordered solvent mol-ecules reside.

| S-EPMC2979648 | biostudies-literature

Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-?N,P}palladium(II) dichloro-methane hemi-solvate.

Project description:There are two independent Pd(II) complex mol-ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol-ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene ligand and two chloride anions.

| S-EPMC2967851 | biostudies-other

Bis[cis-bis-(diphenyl-phosphino)ethene-κP,P']copper(I) tetra-fluoridoborate ethanol solvate.

Project description:In the title compound [Cu(C(26)H(22)P(2))(2)]BF(4)·C(2)H(5)OH, a disordered ethanol solvate molecule and the anions are located in well defined channels along the c axis. The four-coordinate Cu(P-P)(2) core of the cation adopts approximately D(2) point group symmetry with the Cu-P bond lengths spanning a narrow range from 2.272 (1) to 2.285 (1) Å.

| S-EPMC2977563 | biostudies-literature

[Bis(diphenyl-phosphino)methane-κP,P'][bis-(diphenyl-phosphinometh-yl)diethoxy-silane-κP,P']bis-(dinitro-gen)-molybdenum(0) benzene 0.7-solvate.

Project description:In the crystal structure of the title compound, [Mo(C(25)H(22)P(2))(C(30)H(34)O(2)P(2)Si)(N(2))(2)]·0.7C(6)H(6), the Mo atoms are coordinated by four P atoms and two N atoms in a distorted octa-hedral mode. The two C atoms of one of the two eth-oxy groups are disordered and were refined using a split model and site-occupation factors of 0.7:0.3. The crystal structure contains a benzene solvent mol-ecule with a site occupation of 70%.

| S-EPMC2959717 | biostudies-literature

Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-?N,P}platinum(II) dichloro-methane hemisolvate.

Project description:In the title compound, [FePt(C(5)H(5))(C(24)H(19)NP)Cl(2)]·0.5CH(2)Cl(2), the Pt(II) atom adopts a distorted square-planar geometry defined by one P atom and one N atom from the bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferro-cene ligand and two Cl atoms. Two disordered dichloro-methane solvent mol-ecules are each 0.25-occupied on a twofold rotation axis.

| S-EPMC2968145 | biostudies-literature

12-Eth-oxy-2,3,8,9-tetra-methoxy-benzo[c]phenanthridine dichloro-methane solvate.

Project description:The title compound, C(23)H(23)NO(5)·CH(2)Cl(2), was obtained via the alkyl-ation of the 12-hydr-oxy-2,3,8,9-tetra-methoxy-benzo[c]phenanthridine salt. The benzo[c]phenanthridine ring system is essentially planar, with a mean out-of-plane deviation of 0.026?Å. A dicloromethane mol-ecule of solvation is present and located between the sheets of phenanthridine mol-ecules, preventing any significant inter-molecular hydrogen-bonding or ?-? inter-actions.

| S-EPMC2980059 | biostudies-literature

[1,2-Bis(diphenyl-phosphino)-1,2-dicarba-closo-dodeca-borane-κP,P'][7,8-bis-(di-phenyl-phosphino)-7,8-dicarba-nido-undeca-borato-κP,P']gold(I)-dichloro-methane-water (2/1/1).

Project description:The title compound, [Au(C(26)H(30)B(10)P(2))(C(26)H(30)B(9)P(2))]·0.5CH(2)Cl(2)·0.5H(2)O, contains two independent complex mol-ecules in the asymmetric unit. The gold(I) centres display a distorted tetra-hedral geometry. The complex is stablized through weak intra-molecular π-π stacking (Cg⋯Cg = 4.17 Å) and edge-to-face inter-actions (H⋯Cg = 3.21 Å). Adjacent mol-ecules inter-act through C-H⋯π (H⋯Cg = 2.88 Å) and B-H⋯π (H⋯Cg = 3.15 Å) contacts, forming a three-dimensional network, with solvent mol-ecules occupying the cavities. One of the phenyl groups was disordered over two sites with occupancy factors of 0.65 and 0.35.

| S-EPMC2977637 | biostudies-literature

[1,3-Bis(diphenyl-phosphino)propane-?P,P']diiodido(perfluoro-propyl)rhodium(III) dichloro-methane solvate.

Project description:The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110?(2)?K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh-C bond is relatively short at 1.996?(6)?Å. This short metal-carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds.

| S-EPMC2959266 | biostudies-literature

[1,1'-Bis(diphenyl-phosphino)ferrocene]carbon-yl[dihydro-bis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate.

Project description:In the title compound, [FeRu(C(17)H(14)P)(2)(C(6)H(8)BN(4))H(CO)]·C(3)H(6)O, the Ru(II) ion is coordinated in a distorted octa-hedral environment involving a hydride ligand, a carbonyl ligand and two bidentate ligands. Of the two bidentate ligands, the bulky 1,1'-bis-(diphenyl-phosphino)ferrocene (dppf) ligand chelates with a larger bite angle of 101.90 (2)°, whereas the bite angle of the [H(2)Bpz(2)](-) ligand (pz = pyrazol-yl) is 85.67 (7)°. The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand. The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand. In the crystal structure, there are weak inter-molecular C-H⋯O hydrogen bonds between complex mol-ecules and acetone solvent mol-ecules.

| S-EPMC2960072 | biostudies-literature

[N,N-Bis(diphenyl-phosphino)propyl-amine-?P,P']dichloridoplatinum(II).

Project description:The Pt(II) atom in the title compound, [PtCl(2)(C(27)H(27)NP(2))], has a highly distorted square-planar geometry, as evidenced by the P-Pt-P bite angle [72.4?(1)°]. The strain in the complex is further illustrated by the distorted tetra-hedral angles of the P atoms, which range between 93.5?(1) and 122.2?(1)°. It is of inter-est to note that the N atom has to adopt an almost planar geometry with the two P atoms and the C atom attached to it [it is displaced by 0.093?(2)?Å from the CP(2) plane] in order to accommodate the steric bulk of the phenyl groups and the alkyl group of the ligand coordinated to the Pt(II) centre. The mol-ecules pack in horizontal rows across the bc plane. C-H?Cl hydrogen bonds stabilize the crystal packing.

| S-EPMC2980280 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data