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{1-[1-(3-Carboxy-propanamido)eth-yl]-1',2-bis-(diphenyl-phosphino)ferrocene-?P,P'}dichloridoplatinum(II) dichloro-methane 1.25-solvate.

ABSTRACT: The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4?(2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H?O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H?Cl bond leads to an S(8) motif. The solvent is highly disordered and has not been modelled with discrete atoms.

SUBMITTER: Spencer LC

PROVIDER: S-EPMC2915101 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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{1-[1-(3-Carboxy-propanamido)eth-yl]-1',2-bis-(diphenyl-phosphino)ferrocene-κP,P'}dichloridoplatinum(II) dichloro-methane 1.25-solvate.

Spencer Lara C LC Bjelosevic Haris H Darkwa James J Elmroth Sofi K C SK Persson Tina T

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

The dinuclear title compound, [FePtCl(2)(C(17)H(14)P)(C(23)H(23)NO(3)P)]·1.25CH(2)Cl(2), has a slightly distorted cis-PtCl(2)P(2) square-planar geometry around the Pt atom, and the ferrocenylphosphine ligands are staggered at an angle of 29.4 (2)° about Pt. In the crystal structure, the complex forms centrosymmetric dimers via two strong inter-molecular O-H⋯O bonds resulting in R(2) (2)(8) rings. A weak intra-molecular N-H⋯Cl bond leads to an S(8) motif. The solvent is highly disordered and has ...[more]

PMID: 21200513

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