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Bis(?-carboxyl-atoethyl-phospho-nato)bis-[aqua-(2,2'-bipyridine)manganese(II)].

ABSTRACT: The title compound, [Mn(2)(HO(3)PCH(2)CH(2)COO)(2)(C(8)H(8)N(2))(2)(H(2)O)(2)], was obtained by hydro-thermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxy-ethyl-phospho-nate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O-H?O hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distance 4.2754?(4)?Å].

SUBMITTER: Ying SM 

PROVIDER: S-EPMC2915102 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Bis(μ-carboxyl-atoethyl-phospho-nato)bis-[aqua-(2,2'-bipyridine)manganese(II)].

Ying Shao-Ming SM   Chen Yun Y   Luo Qiu-Yan QY   Xv Ya-Ping YP   Liu Dong-Sheng DS  

Acta crystallographica. Section E, Structure reports online 20071212 Pt 1

The title compound, [Mn(2)(HO(3)PCH(2)CH(2)COO)(2)(C(8)H(8)N(2))(2)(H(2)O)(2)], was obtained by hydro-thermal synthesis. The manganese(II) ions are six-coordinate and are linked by two 2-carboxy-ethyl-phospho-nate ligands, forming a centrosymmetric dimer. The Mn ions adopts a distorted octahedral coordination geometry. The dimers are further linked by O-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance 4.2754 (4) Å]. ...[more]

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