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[(1-Azulen-yl)methane-thiol-ato-?S](1,4,8,12-tetra-azacyclo-penta-decane-?N)zinc(II) perchlorate.

ABSTRACT: In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra-azacyclo-penta-decane aza-macrocycle mol-ecule, and one S atom from an azulenylmethane-thiol-ate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiol-ate group in an equatorial position. The Zn-N and Zn-S distances are in the usual ranges for this type of complex.

SUBMITTER: Gorls H

PROVIDER: S-EPMC2915133 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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[(1-Azulen-yl)methane-thiol-ato-κS](1,4,8,12-tetra-azacyclo-penta-decane-κN)zinc(II) perchlorate.

Görls Helmar H Notni Johannes J Anders Ernst E

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra-azacyclo-penta-decane aza-macrocycle mol-ecule, and one S atom from an azulenylmethane-thiol-ate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiol-ate group in an equatorial position. The Zn-N and Zn-S distances are in the usual ranges for this type of complex. ...[more]

PMID: 21200551

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Bis(5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-azacyclo-tetra-decane-?N)(?-l-mal-ato-?O,O:O,O)dinickel(II) bis(perchlorate) monohydrate.

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