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Synthesis, electronic properties and self-assembly on Au{111} of thiolated (oligo)phenothiazines.

ABSTRACT: (Oligo)phenothiazinyl thioacetates, synthesized by a one-pot sequence, are electrochemically oxidizable and highly fluorescent. SAMs can be readily formed from thiols prepared by in situ deprotection of the thioacetates in the presence of a gold-coated silicon wafer. Monolayer formation is confirmed by ellipsometry and the results compared to those obtained by force field and DFT calculations.

SUBMITTER: Franz AW

PROVIDER: S-EPMC2919263 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Synthesis, electronic properties and self-assembly on Au{111} of thiolated (oligo)phenothiazines.

Franz Adam W AW Stoycheva Svetlana S Himmelhaus Michael M Müller Thomas J J TJ

Beilstein journal of organic chemistry 20100702

(Oligo)phenothiazinyl thioacetates, synthesized by a one-pot sequence, are electrochemically oxidizable and highly fluorescent. SAMs can be readily formed from thiols prepared by in situ deprotection of the thioacetates in the presence of a gold-coated silicon wafer. Monolayer formation is confirmed by ellipsometry and the results compared to those obtained by force field and DFT calculations. ...[more]

PMID: 20703376

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