Unknown

Dataset Information

0

Synthesis, electronic properties and self-assembly on Au{111} of thiolated (oligo)phenothiazines.

ABSTRACT: (Oligo)phenothiazinyl thioacetates, synthesized by a one-pot sequence, are electrochemically oxidizable and highly fluorescent. SAMs can be readily formed from thiols prepared by in situ deprotection of the thioacetates in the presence of a gold-coated silicon wafer. Monolayer formation is confirmed by ellipsometry and the results compared to those obtained by force field and DFT calculations.

SUBMITTER: Franz AW 

PROVIDER: S-EPMC2919263 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Synthesis, electronic properties and self-assembly on Au{111} of thiolated (oligo)phenothiazines.

Franz Adam W AW   Stoycheva Svetlana S   Himmelhaus Michael M   Müller Thomas J J TJ  

Beilstein journal of organic chemistry 20100702

(Oligo)phenothiazinyl thioacetates, synthesized by a one-pot sequence, are electrochemically oxidizable and highly fluorescent. SAMs can be readily formed from thiols prepared by in situ deprotection of the thioacetates in the presence of a gold-coated silicon wafer. Monolayer formation is confirmed by ellipsometry and the results compared to those obtained by force field and DFT calculations. ...[more]

Similar Datasets

Unknown Triazolyl Conjugated (Oligo)Phenothiazines Building Blocks for Hybrid Materials-Synthesis and Electronic Properties.
| S-EPMC8156644 | biostudies-literature
Unknown Self-assembly of N-heterocyclic carbenes on Au(111).
| S-EPMC8241988 | biostudies-literature
Unknown Structural and electronic properties of graphene nanoflakes on Au(111) and Ag(111).
| S-EPMC4802307 | biostudies-other
Unknown Electronic Properties of Tetraazaperopyrene Derivatives on Au(111): Energy-Level Alignment and Interfacial Band Formation.
| S-EPMC8450938 | biostudies-literature
Unknown First π-linker featuring mercapto and isocyano anchoring groups within the same molecule: Synthesis, heterobimetallic complexation and self-assembly on Au(111).
| S-EPMC4748958 | biostudies-literature
Unknown Electronic Structure and Luminescence of Quasi-Freestanding MoS2 Nanopatches on Au(111).
| S-EPMC4990308 | biostudies-literature
Unknown Electronic and vibrational surface-enhanced Raman scattering: from atomically defined Au(111) and (100) to roughened Au.
| S-EPMC8162194 | biostudies-literature
Unknown Improving the Switching Capacity of Glyco-Self-Assembled Monolayers on Au(111).
| S-EPMC6973251 | biostudies-literature
Unknown Nanoscale Work Function Contrast Induced by Decanethiol Self-Assembled Monolayers on Au(111).
| S-EPMC7594278 | biostudies-literature
Unknown Structural and electronic properties of uranium-encapsulated Au₁₄ cage.
| S-EPMC5376176 | biostudies-literature