Ontology highlight
ABSTRACT:
SUBMITTER: Cubo L
PROVIDER: S-EPMC2933825 | biostudies-literature | 2010 Sep
REPOSITORIES: biostudies-literature
Journal of inorganic biochemistry 20100428 9
We show that UVA irradiation (365nm) of the Pt(IV) complex trans,trans,trans-[Pt(IV)Cl(2)(OH)(2)(dimethylamine)(isopropylamine)] (1), induces reduction to Pt(II) photoproducts. For the mixed amine Pt(II) complex, trans-[Pt(II)Cl(2)(isopropylamine)(methylamine)] (2), irradiation at 365nm increases the rate and extent of hydrolysis, triggering the formation of diaqua species. Additionally, irradiation increases the extent of reaction of complex 2 with guanosine-5'-monophosphate and affords mainly ...[more]