Dataset Information
Cyano Diels-Alder and cyano ene reactions. Applications in a formal [2 + 2 + 2] cycloaddition strategy for the synthesis of pyridines.
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ABSTRACT:
SUBMITTER: Sakai T
PROVIDER: S-EPMC2944912 | biostudies-literature | 2010 Sep
REPOSITORIES: biostudies-literature
Publications
Cyano Diels-Alder and cyano ene reactions. Applications in a formal [2 + 2 + 2] cycloaddition strategy for the synthesis of pyridines.
Journal of the American Chemical Society 20100901 38
Two metal-free, formal [2 + 2 + 2] cycloaddition strategies for the construction of polycyclic pyridine derivatives are described that proceed via pericyclic cascade mechanisms featuring the participation of unactivated cyano groups as enophile and dienophile cycloaddition partners. ...[more]