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(E)-1-Ferrocenyl-3-(3-nitro-phen-yl)prop-2-en-1-one.

ABSTRACT: In the title compound, [Fe(C(5)H(5))(C(14)H(10)NO(3))], one cyclo-penta-diene ring is substituted and one is unsubstituted. The two rings are almost parallel and are eclipsed and ordered. The conjugated substituent is slightly twisted with respect to the cyclo-penta-diene ring. The crystal structure contains four inter-molecular C-H?O hydrogen-bonds in the range 3.324?(3)-3.539?(3)?Å and one ?(aryl ring)-? (Cp ring) stacking inter-action with a ring-centroid distance of 3.894?(2)?Å.

SUBMITTER: Liu YH

PROVIDER: S-EPMC2959240 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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(E)-1-Ferrocenyl-3-(3-nitro-phen-yl)prop-2-en-1-one.

Liu Yong-Hong YH Ye Jun J Liu Xiao-Lan XL Liu Wen-Long WL Shi Yao-Cheng YC

Acta crystallographica. Section E, Structure reports online 20080906 Pt 10

In the title compound, [Fe(C(5)H(5))(C(14)H(10)NO(3))], one cyclo-penta-diene ring is substituted and one is unsubstituted. The two rings are almost parallel and are eclipsed and ordered. The conjugated substituent is slightly twisted with respect to the cyclo-penta-diene ring. The crystal structure contains four inter-molecular C-H⋯O hydrogen-bonds in the range 3.324 (3)-3.539 (3) Å and one π(aryl ring)-π (Cp ring) stacking inter-action with a ring-centroid distance of 3.894 (2) Å. ...[more]

PMID: 21200999

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