Unknown

Dataset Information

0

(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato-κN)molybdenum(V) benzene solvate.

ABSTRACT: In the title compound, [Mo(C(44)H(28)N(4))(NO(3))O]·C(6)H(6), the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo-O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules.

SUBMITTER: Carter SM 

PROVIDER: S-EPMC2959382 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(Nitrato-κO)oxido(5,10,15,20-tetra-phenyl-porphyrinato-κN)molybdenum(V) benzene solvate.

Carter Shawn M SM   Xu Nan N   Khan Masood A MA   Powell Douglas R DR   Richter-Addo George B GB  

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

In the title compound, [Mo(C(44)H(28)N(4))(NO(3))O]·C(6)H(6), the porphyrin ring is centrosymmetric. The Mo atom, oxide ion and nitrate ion are equally disordered over two sites, such that the Mo atom is displaced by 0.366 (1) Å towards the oxide ion from the 24-atom mean plane of the porphyrin, and also makes a long Mo-O bond to a nitrate O atom. A centrosymmetric benzene solvent mol-ecule is situated between adjacent porphyrin mol-ecules. ...[more]

Similar Datasets

Unknown Tri-μ-oxido-bis-[(5,10,15,20-tetra-phenyl-porphyrinato-κN)niobium(V)].
| S-EPMC3151801 | biostudies-literature
Unknown (2,3,5,6-Tetra-fluoro-phenolato-κO)(5,10,15,20-tetra-phenyl-porphyrinato)iron(III).
| S-EPMC3790366 | biostudies-literature
Unknown Chloridonitros-yl[meso-5,10,15,20-tetra-kis-(p-tol-yl)porphyrinato-κN,N',N'',N''']osmium(II) tetra-hydro-furan tetra-solvate.
| S-EPMC3051540 | biostudies-literature
Unknown Substitutional disorder in bis-[(cyanato-κO)/hydroxido(0.5/0.5)](5,10,15,20-tetra-phenyl-porphyrinato-κN)tin(IV).
| S-EPMC3152010 | biostudies-literature
Unknown [5,10,15,20-Tetra-kis(4-meth-oxy-phen-yl)porphyrinato-κN,N',N'',N'''](trifluoro-methane-sulfonato-κO)-iron(III).
| S-EPMC3051595 | biostudies-literature
Unknown (5,10,15,20-Tetra-phenyl-porphyrinato-κN)cobalt(II)-18-crown-6 (1/1).
| S-EPMC2979047 | biostudies-literature
Unknown μ-2,3,5,6-Tetra-2-pyridylpyrazine-κN,N,N:κN,N,N-bis-[(methanol-κO)(nitrato-κO,O')(nitrato-κO)cadmium(II)].
| S-EPMC2961967 | biostudies-literature
Unknown Crystal structure of an unknown solvate of (piperazine-κN){5,10,15,20-tetra-kis-[4-(benzo-yloxy)phen-yl]porphyrinato-κ(4) N}zinc.
| S-EPMC4992910 | biostudies-literature
Unknown Chlorido{5,10,15,20-tetra-kis-[2-(2,2-dimethyl-propanamido)-phen-yl]porphyrinato-κN,N',N'',N'''}iron(III) chloro-benzene hemisolvate monohydrate.
| S-EPMC3099838 | biostudies-literature
Unknown (1-Methyl-1H-imidazole-κN (3))(1-methyl-2-nitroso-benzene-κN)(5,10,15,20-tetra-phenyl-porphyrinato-κ(4) N)iron(II) di-chloro-methane monosolvate.
| S-EPMC3998258 | biostudies-literature