Unknown

Dataset Information

0

Diaqua-bis(4-bromo-2-formyl-phenolato-?O,O')cobalt(II).


ABSTRACT: In the title complex, [Co(C(7)H(4)BrO(2))(2)(H(2)O)(2)], the Co(II) ion, which lies on a crystallographic inversion center, is coordin-ated by four O atoms from two bidentate 4-bromo-2-formyl-phenolate ligands and two O atoms from two water ligands in a slightly distorted octa-hedral environment. In the crystal structure, one-dimensional chains are formed through inter-molecular O-H?O hydrogen bonds, which are further linked into a two-dimensional network through Br?Br inter-actions [Br?Br = 3.772?(4)?Å].

SUBMITTER: Xiao Y 

PROVIDER: S-EPMC2959384 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

altmetric image

Publications

Diaqua-bis(4-bromo-2-formyl-phenolato-κO,O')cobalt(II).

Xiao Yu Y   Zhang Min M  

Acta crystallographica. Section E, Structure reports online 20080906 Pt 10


In the title complex, [Co(C(7)H(4)BrO(2))(2)(H(2)O)(2)], the Co(II) ion, which lies on a crystallographic inversion center, is coordin-ated by four O atoms from two bidentate 4-bromo-2-formyl-phenolate ligands and two O atoms from two water ligands in a slightly distorted octa-hedral environment. In the crystal structure, one-dimensional chains are formed through inter-molecular O-H⋯O hydrogen bonds, which are further linked into a two-dimensional network through Br⋯Br inter-actions [Br⋯Br = 3.7  ...[more]

Similar Datasets

| S-EPMC2972068 | biostudies-literature
| S-EPMC3414145 | biostudies-literature
| S-EPMC2968947 | biostudies-literature
| S-EPMC3007909 | biostudies-literature
| S-EPMC2924215 | biostudies-literature
| S-EPMC3120375 | biostudies-literature
| S-EPMC2960203 | biostudies-literature
| S-EPMC2979620 | biostudies-literature
| S-EPMC2914936 | biostudies-literature
| S-EPMC3238601 | biostudies-literature