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Diaqua-(2,2'-bipyridine-5,5'-dicarboxyl-ato-?N,N')(ethyl-enediamine-?N,N')copper(II) 2.5-hydrate.

ABSTRACT: In the mol-ecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octa-hedral configuration by two N atoms from a 2,2'-bipyridine-5,5'-dicarboxyl-ate anion, two N atoms from ethyl-enediamine and two O atoms from two water mol-ecules. There are also two and a half water mol-ecules in the asymmetric unit. The planar five-membered ring is nearly coplanar with the adjacent pyridine rings, while the other five-membered ring adopts a twisted conformation, probably due to hydrogen bonding. In the crystal structure, intra- and inter-molecular N-H?O and O-H?O hydrogen bonds link the mol-ecules.

SUBMITTER: Yousefi M

PROVIDER: S-EPMC2959425 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Diaqua-(2,2'-bipyridine-5,5'-dicarboxyl-ato-κN,N')(ethyl-enediamine-κN,N')copper(II) 2.5-hydrate.

Yousefi Mohammad M Khalighi Aida A Tadayon Pour Nasim N Amani Vahid V Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20080920 Pt 10

In the mol-ecule of the title compound, [Cu(C(12)H(6)N(2)O(4))(C(2)H(8)N(2))(H(2)O)(2)]·2.5H(2)O, the Cu(II) atom is six-coordinated in a distorted octa-hedral configuration by two N atoms from a 2,2'-bipyridine-5,5'-dicarboxyl-ate anion, two N atoms from ethyl-enediamine and two O atoms from two water mol-ecules. There are also two and a half water mol-ecules in the asymmetric unit. The planar five-membered ring is nearly coplanar with the adjacent pyridine rings, while the other five-membered ...[more]

PMID: 21201030

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