Bis(ethano-lato-κO)(5,10,15,20-tetra-phenyl-calix[4]pyrrole)manganese(III) hexa-fluoro-phosphate.

ABSTRACT: The title compound, [Mn(C(2)H(5)O)(2)(C(44)H(28)N(4))]PF(6), was synthesized from manganese(III) 2,4-penta-nedionate and 5,10,15,20-tetra-phenyl-calix[4]pyrrole by a hydro-thermal reaction. The Mn(III) atom is located on an inversion centre and the asymmetric unit comprises one half-formula unit. The Mn(III) ion is hexa-coordinated by four N atoms from one 5,10,15,20-tetra-phenyl-calix[4]pyrrole ligand and two O atoms from two deprotonated ethanol mol-ecules. The equatorially located atoms (the Mn and four N atoms) are planar. The dihedral angles between the planes of the phenyl rings and the equatorial plane are 53.3 (2) and 81.8 (2)°. One hexa-fluoro-phosphate anion balances the charge.

SUBMITTER: Wang S 

PROVIDER: S-EPMC2959478 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature