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Tris{N-[(anthracen-9-yl)methyl-ene-amino]thio-ureato}cobalt(III) tetra-hydrate.

ABSTRACT: In the title complex, [Co(C(16)H(12)N(3)S)(3)]·4H(2)O, the central Co(III) atom is in a distorted octa-hedral coordination environment. There are three N-[(anthracen-9-yl)-methyl-ene-amino]-thio-ureate ligands coordinated to the Co(III) atom via three imine N and three thio-amide S atoms. The Co-S and Co-N bond distances are in expected ranges [2.2194?(8)-2.2545?(8) and 1.926?(2)-1.985?(2)Å, respectively]. The endocyclic S-Co-N bond angles in the five-membered chelate rings range from 82.91?(7) to 85.33?(7)°. The structure contains four water mol-ecules which are disordered over 12 sites and link the complex mol-ecules into a three-dimensional network through N-H?O, O-H?O, O-H?N, and O-H?S hydrogen bonds.

SUBMITTER: Zhao J

PROVIDER: S-EPMC2959531 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Tris{N-[(anthracen-9-yl)methyl-ene-amino]thio-ureato}cobalt(III) tetra-hydrate.

Zhao Jianying J Zhang Yu Y

Acta crystallographica. Section E, Structure reports online 20081004 Pt 11

In the title complex, [Co(C(16)H(12)N(3)S)(3)]·4H(2)O, the central Co(III) atom is in a distorted octa-hedral coordination environment. There are three N-[(anthracen-9-yl)-methyl-ene-amino]-thio-ureate ligands coordinated to the Co(III) atom via three imine N and three thio-amide S atoms. The Co-S and Co-N bond distances are in expected ranges [2.2194 (8)-2.2545 (8) and 1.926 (2)-1.985 (2)Å, respectively]. The endocyclic S-Co-N bond angles in the five-membered chelate rings range from 82.91 (7) ...[more]

PMID: 21580817

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