Ontology highlight
ABSTRACT:
SUBMITTER: Zhao J
PROVIDER: S-EPMC2959531 | biostudies-literature | 2008 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20081004 Pt 11
In the title complex, [Co(C(16)H(12)N(3)S)(3)]·4H(2)O, the central Co(III) atom is in a distorted octa-hedral coordination environment. There are three N-[(anthracen-9-yl)-methyl-ene-amino]-thio-ureate ligands coordinated to the Co(III) atom via three imine N and three thio-amide S atoms. The Co-S and Co-N bond distances are in expected ranges [2.2194 (8)-2.2545 (8) and 1.926 (2)-1.985 (2)Å, respectively]. The endocyclic S-Co-N bond angles in the five-membered chelate rings range from 82.91 (7) ...[more]