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Bis(1,10-phenanthroline-?N,N')(phenyl-acetato-?O)copper(II) phenyl-acetate hexa-hydrate.

ABSTRACT: In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol-ecules are inter-connected by hydrogen bonds, completing dodeca-water (H(2)O)(12) clusters which are hydrogen bonded to the carboxyl-ate groups of phenyl-acetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains are hydrogen bonds from water mol-ecules to the carboxyl-ate O atoms belonging to the phenyl-acetato ligands.

SUBMITTER: Tu BT

PROVIDER: S-EPMC2959544 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Bis(1,10-phenanthroline-κN,N')(phenyl-acetato-κO)copper(II) phenyl-acetate hexa-hydrate.

Tu Bing-Tian BT Xie Hong-Zhen HZ Ren Ying-Tao YT Chen Jing-Zhong JZ

Acta crystallographica. Section E, Structure reports online 20081031 Pt 11

In the title compound, [Cu(C(8)H(7)O(2))(C(12)H(8)N(2))(2)](C(8)H(7)O(2))·6H(2)O, the Cu atom is in a distorted square-pyramidal coordination environment. The six crystallographically independent uncoordinated water mol-ecules are inter-connected by hydrogen bonds, completing dodeca-water (H(2)O)(12) clusters which are hydrogen bonded to the carboxyl-ate groups of phenyl-acetate anions, building up one-dimensional anionic chains propagating along [100]. Between the cationic and anionic chains ar ...[more]

PMID: 21580909

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