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Poly[[diaqua-?(2)-hydroxido-(?(7)-2-phos-pho-nato-ethane-sulfonato)-dicopper(II)] trihydrate].


ABSTRACT: The crystal structure of the title compound, [Cu(2)(C(2)H(4)O(6)PS)(OH)(H(2)O)(2)]·3H(2)O, consists of two Cu(2+) ions, one (O(3)PC(2)H(4)SO(3))(3-) ion and one OH(-) ion, as well as five water mol-ecules, two of which are coordinated to Cu(2+). The Cu(2+) ions are coordinated by six O atoms. The CuO(6) polyhedra are connected by ?- and ?(3)-O atoms into zigzag chains along the b axis. These chains are further connected by -CH(2)CH(2)- groups to form layers, in turn building a three-dimensional framework via hydrogen bonding.

SUBMITTER: Sonnauer A 

PROVIDER: S-EPMC2959580 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Poly[[diaqua-μ(2)-hydroxido-(μ(7)-2-phos-pho-nato-ethane-sulfonato)-dicopper(II)] trihydrate].

Sonnauer Andreas A   Lieb Alexandra A   Stock Norbert N  

Acta crystallographica. Section E, Structure reports online 20081018 Pt 11


The crystal structure of the title compound, [Cu(2)(C(2)H(4)O(6)PS)(OH)(H(2)O)(2)]·3H(2)O, consists of two Cu(2+) ions, one (O(3)PC(2)H(4)SO(3))(3-) ion and one OH(-) ion, as well as five water mol-ecules, two of which are coordinated to Cu(2+). The Cu(2+) ions are coordinated by six O atoms. The CuO(6) polyhedra are connected by μ- and μ(3)-O atoms into zigzag chains along the b axis. These chains are further connected by -CH(2)CH(2)- groups to form layers, in turn building a three-dimensional  ...[more]

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