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(2,9-Dieth-oxy-1,10-phenanthroline-?N,N')bis-(thio-cyanato-?N)cobalt(II).

ABSTRACT: In the title complex, [Co(NCS)(2)(C(16)H(16)N(2)O(2))], the Co(II) ion is coordinated by two N atoms from one 2,9-dieth-oxy-1,10-phenanthroline ligand and two N atoms from two different thio-cyanate ligands in a distorted tetra-hedral environment. The Co-N bonds involving the thio-cyanate ligands are significantly shorter than the other two Co-N bonds. The atoms of one of the eth-oxy groups are essentially coplanar with the phenanthroline ring [N=C-O-C = 178.8?(4)°], while the other eth-oxy group is slightly twisted from the phenanthroline ring plane [N=C-O-C = 167.2?(4)°]. In the crystal structure, there is a weak ?-? stacking inter-action between two symmetry-related phenanthroline rings with a centroid-centroid distance of 3.706?(4)?Å.

SUBMITTER: Zheng XF 

PROVIDER: S-EPMC2959597 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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(2,9-Dieth-oxy-1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)cobalt(II).

Zheng Xian-Fu XF   Su Hui H   Zhou Zhan-Fang ZF   Kou Chun-Hong CH   Niu Cao-Yuan CY  

Acta crystallographica. Section E, Structure reports online 20081031 Pt 11

In the title complex, [Co(NCS)(2)(C(16)H(16)N(2)O(2))], the Co(II) ion is coordinated by two N atoms from one 2,9-dieth-oxy-1,10-phenanthroline ligand and two N atoms from two different thio-cyanate ligands in a distorted tetra-hedral environment. The Co-N bonds involving the thio-cyanate ligands are significantly shorter than the other two Co-N bonds. The atoms of one of the eth-oxy groups are essentially coplanar with the phenanthroline ring [N=C-O-C = 178.8 (4)°], while the other eth-oxy grou  ...[more]

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