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Dichlorido{?-6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl-formamide solvate.

ABSTRACT: In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb(II) atom is coordinated in a distorted octa-hedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide mol-ecule and one Cl atom. The dimethyl sulfoxide mol-ecule is disordered over two positions, with site occupancies of 0.576?(2) and 0.424?(2).

SUBMITTER: Wang H

PROVIDER: S-EPMC2959625 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Dichlorido{μ-6,6'-dimeth-oxy-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N,N-dimethyl-formamide solvate.

Wang Hailong H Zhang Daopeng D Tian Laijin L Zhang Li-Fang LF

Acta crystallographica. Section E, Structure reports online 20081025 Pt 11

In the heterodinuclear complex of the title compound, [PbZn(C(22)H(18)N(2)O(4))Cl(2)(C(2)H(6)OS)]·C(3)H(7)NO, the Zn(II) atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The Pb(II) atom is coordinated in a distorted octa-hedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide mol-ecule and one Cl atom. The dimethyl sulfoxide mol ...[more]

PMID: 21580898

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