Ontology highlight
ABSTRACT:
SUBMITTER: Chen YT
PROVIDER: S-EPMC2959631 | biostudies-literature | 2008 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20081009 Pt 11
In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetra-dentate N,N'-bis-(2-oxidobenzyl-idene)-1,2-diphenyl-ethane-1,2-diamine ligand [Co-N = 1.900 (3) and 1.903 (3) Å; Co-O = 1.885 (3) and 1.891 (3) Å] and two pyridine ligands [Co-N = 1.967 (4) and 1.977 (3) Å] in a distorted octa-hedral geometry. The packing of the cations and anions forms voids of 258 Å(3), which are filled by methanol and solvent water mol-ecules wi ...[more]