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Benzyl N'-(1H-indol-3-ylmethyl-idene)-hydrazinecarbodithio-ate.

ABSTRACT: The C(10)H(8)N(3)S(2) portion of the title mol-ecule, C(17)H(15)N(3)S(3), is nearly planar (r.m.s. deviation 0.05?Å); this unit and the phenyl ring subtend an angle of 114.5?(2)° at the methyl-ene C atom.

SUBMITTER: Khaledi H

PROVIDER: S-EPMC2959648 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Benzyl N'-(1H-indol-3-ylmethyl-idene)-hydrazinecarbodithio-ate.

Khaledi Hamid H Mohd Ali Hapipah H Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20081011 Pt 11

The C(10)H(8)N(3)S(2) portion of the title mol-ecule, C(17)H(15)N(3)S(3), is nearly planar (r.m.s. deviation 0.05 Å); this unit and the phenyl ring subtend an angle of 114.5 (2)° at the methyl-ene C atom. ...[more]

PMID: 21580971

Similar Datasets

Benzyl N'-(1-methyl-1H-indol-2-ylmethyl-ene)hydrazinecarbodithio-ate.

Project description:In the title compound, C(18)H(17)N(3)S(2), the dihedral angle between the planes of the aromatic ring systems is 83.63?(16)°. In the crystal structure, inversion dimers occur, linked by pairs of N-H?S hydrogen bonds.

| S-EPMC2960023 | biostudies-literature

Benzyl N'-(1-methyl-1H-indol-3-yl-methyl-idene)hydrazinecarbodithio-ate.

Project description:The N'-(1-methyl-1H-indol-3-ylmethyl-idene)hydrazine-carbo-dithio-ate portion of the title mol-ecule, C(18)H(17)N(3)S(2), is nearly planar; this unit and the phenyl ring subtend an angle of 112.9?(2)° at the methyl-ene C atom.

| S-EPMC2959791 | biostudies-literature

Benzyl N'-(1H-indol-2-ylmethyl-ene)hydrazinecarbodithio-ate ethanol hemisolvate.

Project description:In the crystal of the title compound, C(17)H(15)N(3)S(2)·0.5C(2)H(6)O, the mol-ecules are linked by a pair of N-H(aliphatic)?S hydrogen bonds across a center of inversion, forming a dimer. The ethanol solvent mol-ecule, which is statistically disordered about a crystallographic twofold rotation axis, accepts an N-H(aromatic)?O hydrogen bond; the hydr-oxy group of the solvent mol-ecule is not engaged in hydrogen bonding.

| S-EPMC2959809 | biostudies-other

Benzyl N'-(4,6-dimeth-oxy-2-methyl-3-phenyl-1H-indol-7-ylmethyl-ene)hydrazinecarbodithio-ate.

Project description:The asymmetric unit of the title compound, C(26)H(25)N(3)O(2)S(2), contains two independent mol-ecules, which are linked by a pair of N-H?S hydrogen bonds, forming a dimer.

| S-EPMC2959810 | biostudies-other

Benzyl N'-(2-chloro-benzyl-idene)hydrazinecarbodithio-ate.

Project description:The asymmetric unit of the title compound, C(15)H(13)ClN(2)S(2), contains two independent mol-ecules, which are linked into a pseudo-centrosymmetric dimer by inter-molecular N-H?S hydrogen bonds. The aromatic rings form dihedral angles of 67.06?(3) and 81.85?(2)° in the two independent mol-ecules.

| S-EPMC2960048 | biostudies-literature

N'-(5-Bromo-1H-indol-3-ylmethyl-idene)-3,4,5-trihydroxy-benzohydrazide.

Project description:The two aromatic parts of the title mol-ecule, C(16)H(12)BrN(3)O(4), are connected through a conjugated -CH=N-NH-C(O)- fragment to furnish an almost planar mol-ecule. Adjacent mol-ecules are linked by N-H?O and O-H?O hydrogen bonds into a three-dimensional network. An intramolecular O-H?O link also occurs.

| S-EPMC2959687 | biostudies-literature

Bis[benzyl N'-(1H-indol-3-ylmethyl-ene)hydrazinecarbodithio-ato-?N',S]nickel(II) N,N-dimethyl-formamide disolvate.

Project description:In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry ) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37?(13)°. In the crystal structure, an N-H?O hydrogen bond links the complex to the dimethyl-formamide solvent mol-ecule.

| S-EPMC2959798 | biostudies-other

2-Hydr-oxy-(2-methyl-1H-indol-3-ylmethyl-idene)benzohydrazide ethanol solvate.

Project description:In the title compound, C(17)H(15)N(3)O(2)·C(2)H(6)O, Schiff base molecules are linked by a hydr-oxy-amido hydrogen bond into a helical chain running along the b axis. This chain is consolidated by two other hydrogen bonds; the ethanol solvent mol-ecule is a hydrogen-bond donor to the amide group and a hydrogen-bond acceptor for the indolyl NH group of an adjacent Schiff base mol-ecule.

| S-EPMC2961492 | biostudies-literature

3,4,5-Trihydr-oxy-N'-(1H-indol-2-ylmethyl-idene)benzohydrazide-1H-indole-2-carbaldehyde azine-methanol (2/1/2).

Project description:The title compound, 2C(16)H(13)N(3)O(4)·C(18)H(14)N(4)·2CH(4)O, was crystallized from the reaction between 3,4,5-trihydroxy-benzoyl-hydrazine and indole-2-carbaldehyde in a mixture of ethanol and methanol. The compound is a stoichiometric 2:1 cocrystal of the methanol-solvated reaction product, 3,4,5-trihydr-oxy-N'-(1H-indol-2-ylmethyl-idene)benzohydrazide and 1H-indole-2-carbaldehyde azine that arose unexpectedly during the synthesis. The former mol-ecules are linked by O-H?O hydrogen bonds and also by ?-? stacking inter-actions between benzoyl-hydrazide rings into a two-dimensional network. The methanol solvent mol-ecules are hydrogen bonded to this network. The centrosymmetric azine mol-ecules are not engaged in hydrogen bonding.

| S-EPMC2980105 | biostudies-literature

N-[1-(2-Hydroxy-phen-yl)ethyl-idene]-N-(1H-indol-3-ylmethyl-ene)carbonic dihydrazide.

Project description:In the crystal structure of the title compound {alternative name: 1-[1-(2-hydroxy-phen-yl)ethyl-ideneamino]-3-(1H-indol-3-ylmethyl-eneamino)urea}, C(18)H(17)N(5)O(2), the planar indole component is twisted at an angle of 63.7?(10)° with respect to the rest of the mol-ecule. This compound is one of a series being studied for biological activity. The hydr-oxy groups are involved in both intra-molecular (O-H?N) and inter-molecular (N-H?O) hydrogen bonds.

| S-EPMC2960057 | biostudies-literature

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