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2-Amino-pyridinium 4-hydroxy-benzoate.


ABSTRACT: In the title compound, C(5)H(7)N(2) (+)·C(7)H(5)O(3) (-), the carboxyl-ate mean plane of the 4-hydroxy-benzoate anion is twisted by 8.78?(5)° from the attached ring. The cations and anions are linked via O-H?O, N-H?O and C-H?O hydrogen bonds, forming a three-dimensional network. In addition, ?-? inter-actions involving the benzene and pyridinium rings, with centroid-centroid distances of 3.5500?(6) and 3.6594?(6)?Å, are observed.

SUBMITTER: Quah CK 

PROVIDER: S-EPMC2959658 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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2-Amino-pyridinium 4-hydroxy-benzoate.

Quah Ching Kheng CK   Jebas Samuel Robinson SR   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20081031 Pt 11


In the title compound, C(5)H(7)N(2) (+)·C(7)H(5)O(3) (-), the carboxyl-ate mean plane of the 4-hydroxy-benzoate anion is twisted by 8.78 (5)° from the attached ring. The cations and anions are linked via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network. In addition, π-π inter-actions involving the benzene and pyridinium rings, with centroid-centroid distances of 3.5500 (6) and 3.6594 (6) Å, are observed. ...[more]

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