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Dichlorido[2,2'-(oxydimethyl-ene)dipyridine]copper(II).

ABSTRACT: In the title complex, [CuCl(2)(C(12)H(12)N(2)O)], the Cu(II) ion is coordinated in a distorted trigonal-bipyramidal environment. In the crystal structure, there is a weak ?-? stacking inter-action between symmetry-related pyridine rings, with a centroid-to-centroid distance of 3.8134?(17)?Å. In addition, there is relatively close contact between the pyridine ring ?-system and a symmetry-related Cu(II) ion (Cu?centroid distance of 3.868?Å).

SUBMITTER: Li JM

PROVIDER: S-EPMC2959670 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Dichlorido[2,2'-(oxydimethyl-ene)dipyridine]copper(II).

Li Jin Min JM

Acta crystallographica. Section E, Structure reports online 20081031 Pt 11

In the title complex, [CuCl(2)(C(12)H(12)N(2)O)], the Cu(II) ion is coordinated in a distorted trigonal-bipyramidal environment. In the crystal structure, there is a weak π-π stacking inter-action between symmetry-related pyridine rings, with a centroid-to-centroid distance of 3.8134 (17) Å. In addition, there is relatively close contact between the pyridine ring π-system and a symmetry-related Cu(II) ion (Cu⋯centroid distance of 3.868 Å). ...[more]

PMID: 21580904

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