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Bis(2-amino-pyridine-?N)silver(I) nitrate.

ABSTRACT: The asymmetric unit of the title compound, [Ag(C(5)H(6)N(2))(2)]NO(3), consists of one and a half each of both cations and anions, the other halves being generated by crystallographic inversion centres. One of the Ag(I) atoms lies on an inversion center and one of the nitrate ions is disordered across an inversion center. Each Ag(I) atom is bicoordinated in a linear geometry by two N atoms from two 2-amino-pyridine ligands. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to (001) by N-H?O and C-H?O hydrogen bonds.

SUBMITTER: Fun HK

PROVIDER: S-EPMC2959721 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Bis(2-amino-pyridine-κN)silver(I) nitrate.

Fun Hoong-Kun HK John Jain J Jebas Samuel Robinson SR Balasubramanian T T

Acta crystallographica. Section E, Structure reports online 20081004 Pt 11

The asymmetric unit of the title compound, [Ag(C(5)H(6)N(2))(2)]NO(3), consists of one and a half each of both cations and anions, the other halves being generated by crystallographic inversion centres. One of the Ag(I) atoms lies on an inversion center and one of the nitrate ions is disordered across an inversion center. Each Ag(I) atom is bicoordinated in a linear geometry by two N atoms from two 2-amino-pyridine ligands. In the crystal structure, the cations and anions are linked into a two-d ...[more]

PMID: 21580820

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