Browse
Submit Data
Databases
API
Help

Dataset Information

23 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

2-(Benzene-sulfonamido)acetic acid.

ABSTRACT: The title compound, C(8)H(9)NO(4)S, is of inter-est as a precursor to biologically active sulfur-containing heterocyclic cmpounds. The crystal structure displays the classical O-H?O inter-molecular hydrogen bonding typical for carboxylic acids forming dimers. Symmetry-related dimers are, in turn, linked through head-to-tail pairs of inter-molecular N-H?O inter-actions, giving rise to a zigzag chain along the c axis.

SUBMITTER: Arshad MN

PROVIDER: S-EPMC2959830 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

2-(Benzene-sulfonamido)acetic acid.

Arshad Muhammad Nadeem MN Khan Islam Ullah IU Zia-Ur-Rehman Muhammad M

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

The title compound, C(8)H(9)NO(4)S, is of inter-est as a precursor to biologically active sulfur-containing heterocyclic cmpounds. The crystal structure displays the classical O-H⋯O inter-molecular hydrogen bonding typical for carboxylic acids forming dimers. Symmetry-related dimers are, in turn, linked through head-to-tail pairs of inter-molecular N-H⋯O inter-actions, giving rise to a zigzag chain along the c axis. ...[more]

PMID: 21581263

Similar Datasets

2-(4-Bromo-benzene-sulfonamido)acetic acid.

Project description:The title compound, C(8)H(8)BrNO(4)S, a halogenated sulfon-amide, was prepared by basic hydrolysis of the methyl ester. In the crystal, mol-ecules form centrosymmetric hydrogen-bonded dimers via the carboxyl groups. These dimers are further linked by N-H?O inter-actions involving the carbonyl O and amide H atoms, forming a ribbon-like structure propagating in [010]. These ribbons are further linked via C-H?O inter-actions, forming a three-dimensional network.

| S-EPMC2977417 | biostudies-literature

2-(4-Methyl-benzene-sulfonamido)-2-phenyl-acetic acid.

Project description:In the title compound, C(15)H(15)NO(4)S, the dihedral angle between the phenyl and benzene rings is 46.0 (3)° and a weak intra-molecular N-H⋯O inter-action is present. The crystal structure is stabilized by inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds.

| S-EPMC2971098 | biostudies-literature

2-(4-Bromo-benzene-sulfonamido)-2-phenyl-acetic acid monohydrate.

Project description:In the title compound, C(14)H(12)BrNO(4)S·H(2)O, the phenyl and benzene rings are inclined at a dihedral angle of 39.5?(5)°. The crystal packing is stabilized by N-H?O, C-H?O and O-H?O hydrogen-bonding inter-actions.

| S-EPMC2977332 | biostudies-literature

2-{1-[(2-Nitro-benzene-sulfonamido)-meth-yl]cyclo-hexyl}acetic acid.

Project description:In the title compound, C(15)H(20)N(2)O(6)S, the C-SO(2)-NH-C torsion angle is 64.54?(14)°. In the mol-ecule, there is a bifurcated N-H?(O,O) hydrogen bond, forming S(7) rings. In the crystal, inversion dimers are formed via O-H?O hydrogen bonds involving the carboxyl group, so forming R(2) (2)(8) rings. These dimers are further linked via pairs of C-H?O hydrogen bonds, forming a C(6) chain propagating along the c-axis direction.

| S-EPMC3254438 | biostudies-literature

4-Benzene-sulfonamido-benzoic acid.

Project description:In the mol-ecule of the title sulfonamide compound, C(13)H(11)NO(4)S, the dihedral angle between the planes of the benzene ring and the carboxyl substituent group is 6.7?(4)°. The two aromatic rings are inclined at 45.36?(15)° to one another. In the crystal, adjacent mol-ecules are linked via classical inter-molecular N-H?O and O-H?O, and non-classical C-H?O hydrogen bonds, which stabilize the crystal structure.

| S-EPMC2972151 | biostudies-literature

2-Benzene-sulfonamido-3-methyl-butyric acid.

Project description:In the crystal structure of the title compound, C(11)H(15)NO(4)S, two independent mol-ecules are present per asymmetric unit; they are dimerized through O-H?O hydrogen bonds between their carb-oxy groups to generate R(2) (2)(8) loops. An intra-molecular N-H?O link in one of the mol-ecules closes an S(5) ring. The dimers are linked by N-H?O and C-H?O hydrogen bonds to form a three-dimensional network. The C atoms of the isopropyl group of one of the mol-ecules are disordered over two orientations in a 3:1 ratio.

| S-EPMC3435689 | biostudies-literature

3-[4-(Acetamido)-benzene-sulfonamido]-benzoic acid.

Project description:In the title compound, C(15)H(14)N(2)O(5)S, the dihedral angle between the aromatic rings is 63.20?(11)?Å. The crystal structure displays classical inter-molecular O-H?O hydrogen bonding typical for carb-oxy-lic acids, forming centrosymmetric dimers. These dimers are further connected by N-H?O and C-H?O hydrogen bonds to form an extended network.

| S-EPMC3050169 | biostudies-literature

2-(4-Bromo-benzene-sulfonamido)benzoic acid.

Project description:In the title compound, C(13)H(10)BrNO(4)S, the dihedral angle between the benzene rings is 82.75?(15)°. An intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. In the crystal structure, two mol-ecules form an R(2) (2)(8) centrosymmetric dimer through a pair of O-H?O hydrogen bonds. Intra- and inter-molecular C-H?O hydrogen bonds are also observed.

| S-EPMC2969408 | biostudies-literature

5-Benzene-sulfonamido-2-chloro-benzoic acid.

Project description:In the title compound, C(13)H(10)ClNO(4)S, the dihedral angle between the aromatic ring planes is 87.07 (6)° and an intra-molecular C-H⋯O inter-action occurs. In the crystal, inversion dimers linked by two O-H⋯O hydrogen bonds arise from the carboxyl groups. N-H⋯O hydrogen bonds link the dimers into chains and short C-Cl⋯π and S-O⋯π contacts are also seen.

| S-EPMC2968977 | biostudies-literature

4-(4-Bromo-benzene-sulfonamido)benzoic acid.

Project description:The title compound, C(13)H(10)BrNO(4)S, belongs to the sulfonamide class of organic compounds. The two aromatic rings are inclined at 34.30 (15)° to one another, and the carboxyl substituent lies in the plane of the benzene ring to which it is bound (maximum deviation = 0.004 Å). In the crystal structure, charactersitic carboxylic acid dimers are formed through O-H⋯O hydrogen bonds. These dimers are linked into rows down a by N-H⋯O inter-actions. Additional C-H⋯O contacts further stabilize the structure, and a close Br⋯Br(x, -y + 1, -z + 1) contact of 3.5199 (9) Å is also observed.

| S-EPMC2977752 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data