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4-Chloro-N-(3-phenyl-allyl-idene)aniline.

ABSTRACT: In the title mol-ecule, C(15)H(12)ClN, the C=N and C=C bond lengths are 1.273 (2) and 1.324 (2) Å, respectively. The two aromatic rings form a dihedral angle of 3.27 (3)°.

SUBMITTER: Zhang BX

PROVIDER: S-EPMC2959977 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(E)-4-Chloro-N-[(E)-2-methyl-3-phenyl-allyl-idene]aniline.

Project description:The title Schiff base compound, C(16)H(14)ClN, adopts E configurations with respect to both the C=C and C=N bonds. The dihedral angle between the two aromatic rings is 53.27?(4)°, while the plane through the C=C-C=N system is inclined at 9.06?(8)° to the benzene ring and 44.92?(5)° to the chloro-benzene ring. In the crystal structure, weak C-H?Cl and C-H?N hydrogen bonds stack the mol-ecules down the a axis.

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(E)-N-(3,3-Di-phenyl-allyl-idene)-2-(tri-fluoro-meth-yl)aniline.

Project description:In the title compound, C22H16F3N, the C=N bond of the central imine group adopts an E conformation. The dihedral angles between the 2-(tri-fluoro-meth-yl)phenyl ring and the benzene rings are 9.34?(1) and 68.8?(1)°. The imine group displays a C-C-N=C torsion angle of 41.6?(3)°. In the crystal, weak C-H?F hydrogen bonds link the mol-ecules into chains parallel to the b-axis direction.

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(E)-N-(3,3-Diphenyl-allyl-idene)-4-nitro-aniline.

Project description:In the title compound, C(21)H(16)N(2)O(2), the dihedral angles between the mean planes of the 4-nitro-phenyl ring and the two phenyl rings are 57.3?(5) and 16.8?(6)°. The imine group displays a C-C-N-C torsion angle of -24.9?(3)°.

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(E)-N-(3,3-Diphenyl-allyl-idene)-3-nitro-aniline.

Project description:In the title compound, C(21)H(16)N(2)O(2), the 3-nitro-phenyl and two phenyl rings are twisted from the mean plane of the enimino fragment by 44.4?(1), 37.2?(1) and 74.1?(1)°, respectively. The crystal packing exhibits no classical inter-molecular contacts.

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(Z)-3-Chloro-N-[(Z)-3-(3-chloro-2-methyl-phenyl-imino)-butan-2-yl-idene]-2-methyl-aniline.

Project description:In the title compound, C(18)H(18)Cl(2)N(2), the complete molecule is generated by the application of C(2) symmetry. The C=N bond has an E configuration. The dihedral angle between the benzene ring and the 1,4-diaza-butadiene plane is 66.81?(9)°.

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N'-(3-Phenyl-allyl-idene)isonicotino-hydrazide.

Project description:The asymmetric unit of the title compound, C(15)H(13)N(3)O, contains two similar mol-ecules. Each mol-ecule is non-planar, as indicated by the dihedral angles between the pyridine and benzene rings of 45.2?(2) and 56.6?(2)°. The crystal structure is consolidated by inter-molecular N-H?O hydrogen bonds.

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Project description:In the title compound, C(15)H(13)N(3)O·H(2)O, the dihedral angle between the pyridine and phenyl rings is 35.45 (7)°. Inter-molecular O-H⋯O, O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds are found in the crystal structure. In addition, C-H⋯π inter-actions involving the pyridine and phenyl rings are also found.

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4-Chloro-N-(3,4,5-trimethoxy-benzyl-idene)aniline.

Project description:The title compound, C(16)H(16)ClNO(3), is a Schiff base displaying a trans configuration of the C=N double bond. In the crystal structure, inter-molecular C-H?N and bifurcated C-H?(O,O) hydrogen bonds are observed.

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N-(4-Chloro-benzyl-idene)-4-methoxy-aniline.

Project description:The title compound, C(14)H(12)ClNO, was prepared by the reaction of 4-methoxy-aniline and 4-chloro-benzaldehyde in ethanol at 367?K. The mol-ecule is almost planar, with a dihedral angle between the two benzene rings of 9.1?(2)° and an r.m.s. deviation from the mean plane through all non-H atoms in the mol-ecule of 0.167?Å.

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3-Chloro-1-methyl-4-[2-(3-phenyl-allyl-idene)hydrazinyl-idene]-3,4-dihydro-1H-2?(6),1-benzothia-zine-2,2-dione.

Project description:In the title compound, C(18)H(16)ClN(3)O(2)S, the dihedral angle between the aromatic rings is 4.81?(2)° and the alkyl chain takes on an extended conformation [N-C-C-C = 179.2?(4)°]. The conformation of the thia-zine ring is an envelope, with the S atom displaced by -0.805?(3)?Å from the mean plane of the other five atoms (r.m.s. deviation = 0.046?Å). The Cl atom is an axial conformation and is displaced by 1.761?(4)?Å from the thia-zine ring plane. In the crystal, inversion dimers linked by pairs of C-H?O inter-actions generate R(2) (2)(20) loops and further C-H?O hydrogen bonds link the dimers into (001) sheets. Weak aromatic ?-? stacking inter-actions [centroid-centroid separations = 3.870?(3) and 3.883?(3)?Å] are also observed.

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