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Catena-Poly[[(1,10-phenanthroline)manganese(II)]-?(3)-5-methyl-isophthalato].

ABSTRACT: In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn-N = 2.273?(3) and 2.305?(2)?Å] from a 1,10-phenanthroline ligand and four O atoms [Mn-O = 2.112?(2)-2.343?(3)?Å] from three 5-methyl-isophthalate (mip) ligands in a distorted octa-hedral geometry. Each mip dianion acts as a tetra-dentate ligand connecting three Mn ions. The crystal packing exhibits ?-? inter-actions [3.599?(2)-3.755?(2)?Å] between the centroids of the six-membered rings of neighbouring 1,10-phenanthroline ligands.

SUBMITTER: Yu ZL 

PROVIDER: S-EPMC2960010 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[(1,10-phenanthroline)manganese(II)]-μ(3)-5-methyl-isophthalato].

Yu Zhao-Lian ZL   Hu Jiang-Liang JL  

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

In the title coupound, [Mn(C(9)H(6)O(4))(C(12)H(8)N(2))](n), the Mn(II) ion is coordinated by two N atoms [Mn-N = 2.273 (3) and 2.305 (2) Å] from a 1,10-phenanthroline ligand and four O atoms [Mn-O = 2.112 (2)-2.343 (3) Å] from three 5-methyl-isophthalate (mip) ligands in a distorted octa-hedral geometry. Each mip dianion acts as a tetra-dentate ligand connecting three Mn ions. The crystal packing exhibits π-π inter-actions [3.599 (2)-3.755 (2) Å] between the centroids of the six-membered rings  ...[more]

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