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Methyl (4-bromo-benzene-sulfonamido)acetate.

ABSTRACT: The title compound, C(9)H(10)BrNO(4)S, is an inter-mediate for the formation of benzothia-zines. In the crystal structure, inter-molecular N-H?O hydrogen bonds link the mol-ecules, forming R(2) (2)(10) ring motifs, which are linked into a two-dimensional polymeric sheet through inter-molecular C-H?O hydrogen bonds.

SUBMITTER: Arshad MN

PROVIDER: S-EPMC2960029 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Methyl (4-bromo-benzene-sulfonamido)acetate.

Arshad Muhammad Nadeem MN Tahir M Nawaz MN Khan Islam Ullah IU Ahmad Ejaz E Shafiq Muhammad M

Acta crystallographica. Section E, Structure reports online 20081120 Pt 12

The title compound, C(9)H(10)BrNO(4)S, is an inter-mediate for the formation of benzothia-zines. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules, forming R(2) (2)(10) ring motifs, which are linked into a two-dimensional polymeric sheet through inter-molecular C-H⋯O hydrogen bonds. ...[more]

PMID: 21581352

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Project description:In the title compound, C(11)H(10)N(3)O(4)S(+)·C(2)Cl(3)O(2) (-), the benzene ring forms an angle of 85.21 (13)° with the pyridinium ring. The nitro group is nearly coplanar with its attached benzene ring [dihedral angle = 3.68 (12)°]. In the crystal structure, strong N-H⋯O hydrogen bonds link the ion-pairs. The packing is further consolidated by weak C-H⋯O inter-ations.

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