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Diaqua-bis(2-pyridylphospho-nato N-oxide-?O,O)cobalt(II).

ABSTRACT: In the title complex, [Co(C(5)H(5)NO(4)P)(2)(H(2)O)(2)], the Co(II) ion, which lies on a crystallographic inversion center, is coordin-ated by four O atoms from two bidentate 2-phospho-nato-pyridine N-oxide ligands and two O atoms from two water ligands in a slightly distorted octa-hedral environment. Mol-ecules are inter-linked by three O-H?O hydrogen bonds and one weak C-H?O inter-action, forming a three-dimensional supra-molecular structure.

SUBMITTER: Ma YS

PROVIDER: S-EPMC2960075 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Diaqua-bis(2-pyridylphospho-nato N-oxide-κO,O)cobalt(II).

Ma Yun-Sheng YS Lu Tian-Xian TX

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

In the title complex, [Co(C(5)H(5)NO(4)P)(2)(H(2)O)(2)], the Co(II) ion, which lies on a crystallographic inversion center, is coordin-ated by four O atoms from two bidentate 2-phospho-nato-pyridine N-oxide ligands and two O atoms from two water ligands in a slightly distorted octa-hedral environment. Mol-ecules are inter-linked by three O-H⋯O hydrogen bonds and one weak C-H⋯O inter-action, forming a three-dimensional supra-molecular structure. ...[more]

PMID: 21581161

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