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Penta-carbonyl-2?C-chlorido-1?Cl-bis-[1(?)-cyclo-penta-dien-yl](?-?-oxido-benzyl-idene-1:2?O:C)titanium(IV)tungsten(0).

ABSTRACT: The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1?(2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face ?-? inter-action [3.544?(6)?Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.

SUBMITTER: Esterhuysen C

PROVIDER: S-EPMC2960115 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Penta-carbonyl-2κC-chlorido-1κCl-bis-[1(η)-cyclo-penta-dien-yl](μ-α-oxido-benzyl-idene-1:2κO:C)titanium(IV)tungsten(0).

Esterhuysen Catharine C Nel I B Jacques IB Esterhuysen Matthias W MW Cronje Stephanie S

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule. ...[more]

PMID: 21581149

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