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Poly[4,4'-imino-dipyridinium [di-?(4)-isophthalato-?O:O':O'':O''-di-?(3)-iso-phthal-ato-?O:O':O'';?O:O':O'',O'''-trizinc(II)] dihydrate].

ABSTRACT: In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetra-hedral, octa-hedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate dianions into [Zn(3)(isophthalate)(4)](n) (2n-) anionic layers, which aggregate into the three-dimensional structure via hydrogen-bonding pathways mediated by doubly protonated 4,4'-imino-dipyridinium cations and water mol-ecules of crystallization. One solvent water mol-ecule was found to be disordered over two positions, each with a 50% site-occupancy factor.

SUBMITTER: Braverman MA

PROVIDER: S-EPMC2960139 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Poly[4,4'-imino-dipyridinium [di-μ(4)-isophthalato-κO:O':O'':O''-di-μ(3)-iso-phthal-ato-κO:O':O'';κO:O':O'',O'''-trizinc(II)] dihydrate].

Braverman Maxwell A MA Laduca Robert L RL

Acta crystallographica. Section E, Structure reports online 20081122 Pt 12

In the title compound, {(C(10)H(11)N(3))[Zn(3)(C(8)H(4)O(4))(4)]·2H(2)O}(n), divalent Zn atoms are linked into trinuclear units featuring tetra-hedral, octa-hedral and distorted tetrahedral, octahedral and square-pyramidal coordination geometries. These trinuclear units are connected by isopthalate dianions into [Zn(3)(isophthalate)(4)](n) (2n-) anionic layers, which aggregate into the three-dimensional structure via hydrogen-bonding pathways mediated by doubly protonated 4,4'-imino-dipyridinium ...[more]

PMID: 21581198

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