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Aqua-(4-methyl-quinoline-?N)[N-(2-oxidobenzyl-idene)glycinato-?O,N,O']copper(II) hemihydrate.

ABSTRACT: The title complex, [Cu(C(9)H(7)NO(3))(C(10)H(9)N)(H(2)O)]·0.5H(2)O, crystallizes with two independent formula units in the asymmetric unit; the solvent mol-ecule is located on a twofold axis of symmetry. The Cu(II) atom is coordinated by one tridentate N-salicylideneglycinate Schiff base ligand, one 4-methyl-quinoline ligand and one water mol-ecule, leading to a slightly distorted square-pyramidal N(2)O(3) geometry. In the crystal structure, the mol-ecules are linked by O-H?O hydrogen bonds into linear chains in the [100] direction. The structure is further stabilized by inter-molecular C-H?O inter-actions and C?C contacts with C?C = 3.3058?(2), 3.3636?(2) and 3.3946?(2)?Å.

SUBMITTER: Travnicek Z

PROVIDER: S-EPMC2960168 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Aqua-(4-methyl-quinoline-κN)[N-(2-oxidobenzyl-idene)glycinato-κO,N,O']copper(II) hemihydrate.

Trávníček Zdeněk Z Marek Jaromír J Vančo Ján J Svajlenová Oľga O

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

The title complex, [Cu(C(9)H(7)NO(3))(C(10)H(9)N)(H(2)O)]·0.5H(2)O, crystallizes with two independent formula units in the asymmetric unit; the solvent mol-ecule is located on a twofold axis of symmetry. The Cu(II) atom is coordinated by one tridentate N-salicylideneglycinate Schiff base ligand, one 4-methyl-quinoline ligand and one water mol-ecule, leading to a slightly distorted square-pyramidal N(2)O(3) geometry. In the crystal structure, the mol-ecules are linked by O-H⋯O hydrogen bonds into ...[more]

PMID: 21201263

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