Ontology highlight
ABSTRACT:
SUBMITTER: Bhyrappa P
PROVIDER: S-EPMC2960240 | biostudies-literature | 2008 Jan
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20080109 Pt 2
The title complex, [Cu(C(68)H(44)N(4))]·C(2)H(2)Cl(4), exhibits nearly square-planar geometry around the Cu(II) centre and the macrocyclic ring is almost planar. The porphyrin mol-ecule has an approximate non-crystallographic inversion centre (C(i)), and a non-crystallographic twofold rotation axis (C(2)) within the Cu(II)-porphyrin ring plane. Further, it has non-crystallographic twofold rotation axis and mirror plane (C(s)) symmetry perpendicular to the mol-ecular plane. The mol-ecular packing ...[more]