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N-Hydr-oxy-N-o-tolyl-acetamide.

ABSTRACT: In the mol-ecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intra-molecular O-H?O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37?(3)° with respect to the benzene ring. In the crystal structure, inter-molecular O-H?O hydrogen bonds link the mol-ecules stacked along the b axis. There are also ?-? inter-actions between benzene rings with a face-to-face stacking distance of 3.434?Å.

SUBMITTER: Li YH

PROVIDER: S-EPMC2960255 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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N-Hydr-oxy-N-o-tolyl-acetamide.

Li Yu-Hao YH Liu Rui R Zhang Xiang-Ning XN Zhu Hong-Jun HJ

Acta crystallographica. Section E, Structure reports online 20080130 Pt 2

In the mol-ecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intra-molecular O-H⋯O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37 (3)° with respect to the benzene ring. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules stacked along the b axis. There are also π-π inter-actions between benzene rings with a face-to- ...[more]

PMID: 21201552

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