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[Bis(2-pyridylmeth-yl)amine]dichloridomercury(II).

ABSTRACT: The Hg atom in the title complex, [HgCl(2)(C(12)H(13)N(3))], adopts a square-pyramidal geometry, being ligated by three N atoms of the tridentate bis-(2-pyridylmeth-yl)amine ligand and two Cl atoms, with one of the latter occupying the apical position. Disorder is noted in the amine portion of the ligand and this was modelled over two sites, with the major component having a site-occupancy factor of 0.794?(14).

SUBMITTER: Kim YI

PROVIDER: S-EPMC2960290 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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[Bis(2-pyridylmeth-yl)amine]dichloridomercury(II).

Kim Young-Inn YI Lee You-Soon YS Seo Hoe-Joo HJ Nam Ki-Sun KS Kang Sung Kwon SK

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

The Hg atom in the title complex, [HgCl(2)(C(12)H(13)N(3))], adopts a square-pyramidal geometry, being ligated by three N atoms of the tridentate bis-(2-pyridylmeth-yl)amine ligand and two Cl atoms, with one of the latter occupying the apical position. Disorder is noted in the amine portion of the ligand and this was modelled over two sites, with the major component having a site-occupancy factor of 0.794 (14). ...[more]

PMID: 21201317

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[Benzyl(2-pyridylmeth-yl)amine]dichloridomercury(II).

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Project description:The Hg(II) ion in the title complex, [HgCl(2)(C(13)H(12)N(2))], adopts a distorted tetra-hedral geometry being coordinated by two Cl anions and by two N atoms of the benz-yl(2-pyridyl-methyl-ene)amine ligand. The Cl-Hg-Cl plane is twisted at 70.1 (1)° from the mean plane of the chelate ring. In the crystal structure, inter-molecular π-π inter-actions [centroid-centroid distance = 3.793 (3) Å] between the aromatic rings link the mol-ecules into zigzag chains extending along [010].

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N,N-Bis(2-pyridylmeth-yl)-tert-butyl-amine.

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μ-Oxido-bis-{chlorido[tris-(2-pyridylmeth-yl)amine]chromium(III)} bis(hexafluoridophosphate).

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Di-?-chlorido-bis-{[2-(benzyl-imino-meth-yl)pyridine-?N,N']chloridomercury(II)} dichloridomercury(II).

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catena-Poly[[dichloridozinc(II)]-μ-1,4-bis-(3-pyridylmeth-yl)piperazine].

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