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2-[1-Chloro-3-(2-methyl-5-nitro-1H-imidazol-1-yl)propan-2-yloxycarbonyl]benzoic acid.

ABSTRACT: The asymmetric unit of the title compound, C(15)H(14)ClN(3)O(6), contains two independent mol-ecules. The imidazole rings are oriented with respect to the benzene rings at dihedral angles of 19.66?(3) and 21.64?(3)°. In the crystal structure, inter-molecular O-H?N hydrogen bonds link the mol-ecules into infinite chains.

SUBMITTER: Tao X

PROVIDER: S-EPMC2960386 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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2-[1-Chloro-3-(2-methyl-5-nitro-1H-imidazol-1-yl)propan-2-yloxycarbonyl]benzoic acid.

Tao Xiao X Yuan Lin L Zhang Xiao-Qing XQ Wang Jin-Tang JT

Acta crystallographica. Section E, Structure reports online 20080118 Pt 2

The asymmetric unit of the title compound, C(15)H(14)ClN(3)O(6), contains two independent mol-ecules. The imidazole rings are oriented with respect to the benzene rings at dihedral angles of 19.66 (3) and 21.64 (3)°. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds link the mol-ecules into infinite chains. ...[more]

PMID: 21201498

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Crystal structure of 2-{[1-(2-methyl-5-nitro-1H-imidazol-1-yl)propan-2-yl-oxy]carbon-yl}benzoic acid.

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Project description:In the crystal of the title compound, C7H9N3O4, mol-ecules are linked by weak C-H⋯O hydrogen bonds into chains along the a-axis direction. The dihedral angle between the ring and the nitro group is 3.03 (6), while that between the ring and the acetate group is 85.01 (3)°.

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Crystal structures of four isomeric hydrogen-bonded co-crystals of 6-methyl-quinoline with 2-chloro-4-nitro-benzoic acid, 2-chloro-5-nitro-benzoic acid, 3-chloro-2-nitro-benzoic acid and 4-chloro-2-nitro-benzoic acid.

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Ethyl 2-(2-methyl-4-nitro-1H-imidazol-1-yl)acetate.

Project description:In the title compound, C(8)H(11)N(3)O(4), the dihedral angle between the imidazole ring and the ethyl acetate plane is 103.1 (8)°. The crystal packing is stabilized by weak inter-molecular C-H⋯O and C-H⋯N hydrogen bonds.

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Project description:In the title compound, C(8)H(12)N(4)O(4), the essentially planar methyl-carbamoyloxymethyl group [maximum deviation 0.038?(3)?Å] and the imidazole ring make a dihedral angle of 48.47?(3)°. The crystal packing is stabilized by inter-molecular N-H?N and C-H?O hydrogen bonds, which link the mol-ecules into infinite ribbons running along the a axis, and by weak ?-? stacking inter-actions [centroid-centroid distance = 3.894?(2)?Å].

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Monoclinic polymorph of 4-[(1H-benz-imidazol-1-yl)meth-yl]benzoic acid.

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2-[2-(2-Nitro-phen-yl)-4,5-diphenyl-1H-imidazol-1-yl]-3-phenyl-propan-1-ol.

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