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5,7-Di-2-pyridyl-2,3-dihydro-thieno[3,4-b][1,4]dioxine.

ABSTRACT: The title compound, C(16)H(12)N(2)O(2)S, was prepared by a Neigishi cross-coupling reaction to investigate the coordination chemistry of thio-phene-containing ligands. In the mol-ecule, the pyridine rings are twisted from the thio-phene ring by 20.6?(1) and 4.1?(2)°. The six-membered dihydro-dioxine ring is in a half-chair conformation.

SUBMITTER: Djukic B

PROVIDER: S-EPMC2960398 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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5,7-Di-2-pyridyl-2,3-dihydro-thieno[3,4-b][1,4]dioxine.

Djukic Brandon B Harrington Laura E LE Britten James F JF Lemaire Martin T MT

Acta crystallographica. Section E, Structure reports online 20080116 Pt 2

The title compound, C(16)H(12)N(2)O(2)S, was prepared by a Neigishi cross-coupling reaction to investigate the coordination chemistry of thio-phene-containing ligands. In the mol-ecule, the pyridine rings are twisted from the thio-phene ring by 20.6 (1) and 4.1 (2)°. The six-membered dihydro-dioxine ring is in a half-chair conformation. ...[more]

PMID: 21201489

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Diethyl 2,3-dihydro-thieno[3,4-b]-1,4-dioxine-5,7-dicarboxyl-ate.

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