Browse
Submit Data
Databases
API
Help

Dataset Information

25 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-?N',S]copper(II).

ABSTRACT: The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra-hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol-ecules are inter-connected into chains along the c axis by weak C-H?S inter-molecular inter-actions. The crystal packing is further stabilized by C-H?? inter-actions.

SUBMITTER: Tarafder MT

PROVIDER: S-EPMC2960465 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-κN',S]copper(II).

Tarafder M T H MT Islam M Toihidul MT Islam M A A A A MA Chantrapromma Suchada S Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20080125 Pt 2

The Cu(II) atom of the title complex, [Cu(C(17)H(15)N(2)S(2))(2)], lies on a twofold rotation axis, and is in a distorted tetra-hedral geometry with the two bidentate N(2)S(2) Schiff bases. In the crystal structure, the mol-ecules are inter-connected into chains along the c axis by weak C-H⋯S inter-molecular inter-actions. The crystal packing is further stabilized by C-H⋯π inter-actions. ...[more]

PMID: 21201362

Similar Datasets

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)hydrazinecarbodithio-ato-κN',S]zinc(II).

Project description:In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis. The crystal structure is further stabilized by C-H⋯π inter-actions involving the phenyl ring of the 3-phenyl-prop-2-enyl-idene unit.

| S-EPMC2961027 | biostudies-literature

Bis[benzyl N'-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-?(2)N',S]mercury(II).

Project description:In the title compound, [Hg(C(17)H(15)N(2)S(2))(2)], the Hg(II) ion lies on a crystallographic twofold rotation axis giving a very distorted tetra-hedral coordination geometry best described as bis-phenoidal, being chelated by two deprotonated N,S Schiff base ligands through the azomethine nitro-gen and the thiol-ate sulfur donors. The dihedral angle between the two chelating ligand moieties is 79.75?(10)°. In the crystal, weak C-H?S inter-actions give rise to chains extending along the c axis.

| S-EPMC3393190 | biostudies-literature

Bis[benzyl 3-(3-phenyl-prop-2-enyl-idene)dithio-carbazato-?(2)N(3),S]cadmium.

Project description:In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis-phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol-ate S atom. The dihedral angle between the two chelating ligands is 84.01?(9)°. Weak inter-molecular C-H?S inter-actions lead to the formation of chains along the c axis.

| S-EPMC3393227 | biostudies-literature

Benzyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

Project description:The title compound, C(17)H(16)N(2)S(2), a dithio-carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl-idine group. The 3-phenyl-prop-2-enyl-idene and dithio-carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074?(2)?Å, while the dihedral angle between the 3-phenyl-prop-2-enyl-idene and the benzyl group is 77.78?(7)°. In the crystal structure, mol-ecules are linked by an N-H?S hydrogen bond and a weak C-H?S inter-action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C-H?? inter-actions.

| S-EPMC2961473 | biostudies-literature

Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II).

Project description:In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure.

| S-EPMC2960303 | biostudies-literature

Bis[benzyl N'-(1H-indol-3-ylmethyl-ene)hydrazinecarbodithio-ato-κN',S]nickel(II) N,N-dimethyl-formamide disolvate.

Project description:In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the Ni atom (site symmetry ) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)°. In the crystal structure, an N-H⋯O hydrogen bond links the complex to the dimethyl-formamide solvent mol-ecule.

| S-EPMC2959798 | biostudies-literature

4-Eth-oxy-N-(3-phenyl-prop-2-enyl-idene)aniline.

Project description:The title compound, C(17)H(17)NO, was prepared by the condensation of cinnamaldehyde with p-phenetidine in ethanol. The prop-2-enyl-idene group exhibits an E configuration at the N=C and C=C double bonds, with C-N-C-C and C-C-C-C torsion angles of -179.9?(3) and -175.9?(3)°, respectively. The prop-2-enyl-idene group is not strictly planar [maximum deviation = 0.054?(4)?Å] and forms dihedral angles of 28.0?(3) and 34.9?(3)° with the attached aromatic rings.

| S-EPMC2961520 | biostudies-literature

Methyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate.

Project description:In the title compound, C(11)H(12)N(2)S(2), the dithio-carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl-idene group. The atoms of the propenyl-idene and dithio-carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol-ecules form inversion dimers via pairs of N-H⋯S hydrogen bonds involving the terminal S atom.

| S-EPMC3008995 | biostudies-literature

Benzyl N'-(2-chloro-benzyl-idene)hydrazinecarbodithio-ate.

Project description:The asymmetric unit of the title compound, C(15)H(13)ClN(2)S(2), contains two independent mol-ecules, which are linked into a pseudo-centrosymmetric dimer by inter-molecular N-H⋯S hydrogen bonds. The aromatic rings form dihedral angles of 67.06 (3) and 81.85 (2)° in the two independent mol-ecules.

| S-EPMC2960048 | biostudies-literature

Bis{benzyl 2-[4-(4-meth-oxy-phen-yl)butan-2-yl-idene]hydrazinecarbodithio-ato-?(2)N(2),S}nickel(II).

Project description:The complete mol-ecule of the title complex, [Ni(C(19)H(21)N(2)OS(2))(2)], is generated by the application of twofold symmetry. The Ni(II) atom is N,S-chelated by two hydrazinecarbodithio-ate ligands, which provide an N(2)S(2) donor set that defines a distorted square-planar geometry, the S atoms being approximately cis. The conformation of the chelate ring is an envelope with the Ni(II) atom being the flap atom. The dihedral angle between the least-squares planes through the chelate rings = 30.10?(6)°. Supra-molecular chains propagated by glide symmetry along the c axis and mediated by C-H?N contacts feature in the crystal packing.

| S-EPMC3379070 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data