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Dichlorido(4,4'-di-tert-butyl-2,2'-bi-pyridine-?N,N')gold(III) tetrachlorido-aurate(III) acetonitrile solvate.

ABSTRACT: In the title compound, [AuCl(2)(C(9)H(12)N)(2)][AuCl(4)]·C(2)H(3)N, there is a mirror plane passing through Au and the central C-C bond of the bipyridyl ligand in the cation, and through Au and two Cl atoms of the anion. A cis-AuCl(2)N(2) square-planar geometry for the cation and a square-planar AuCl(4) geometry for the anion result. The two C atoms and the N atom of the acetonitrile mol-ecule all have m site symmetries. In the crystal structure, weak C-H?Cl inter-actions may help to establish the packing.

SUBMITTER: Y?ld?r?m SO

PROVIDER: S-EPMC2960475 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Dichlorido(4,4'-di-tert-butyl-2,2'-bi-pyridine-κN,N')gold(III) tetrachlorido-aurate(III) acetonitrile solvate.

Yıldırım Sema Öztürk SÖ Akkurt Mehmet M Safari Nasser N Amani Vahid V McKee Vickie V McKee Vickie V Abedi Anita A Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20080820 Pt 9

In the title compound, [AuCl(2)(C(9)H(12)N)(2)][AuCl(4)]·C(2)H(3)N, there is a mirror plane passing through Au and the central C-C bond of the bipyridyl ligand in the cation, and through Au and two Cl atoms of the anion. A cis-AuCl(2)N(2) square-planar geometry for the cation and a square-planar AuCl(4) geometry for the anion result. The two C atoms and the N atom of the acetonitrile mol-ecule all have m site symmetries. In the crystal structure, weak C-H⋯Cl inter-actions may help to establish t ...[more]

PMID: 21201629

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