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{?-N-[(Diphenyl-phosphino)meth-yl]pyridin-2-amine-?N:P}bis-{[2-(2,2'-bipyridin-6-yl)phenyl-?N,N',C]platinum(II)} bis-(perchlorate).

ABSTRACT: The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenyl-phosphino)meth-yl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2'-bipyridine (pbpy) ligand in a square-planar geometry. The other Pt atom is coordinated by one N atom from the dppmp ligand, and one C atom and two N atoms from another pbpy ligand in a square-planar geometry. There are intra-molecular ?-? inter-actions between the pbpy ligands, with a centroid-centroid distance of 3.62?(1)?Å between two pyridyl rings. The oxygen atoms of both perchlorate anions are disordered, each over two different positions [occupanicies 0.49?(3)/0.51?(3) and 0.48?(2)/0.52?(2)].

SUBMITTER: Du XD

PROVIDER: S-EPMC2960491 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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{μ-N-[(Diphenyl-phosphino)meth-yl]pyridin-2-amine-κN:P}bis-{[2-(2,2'-bipyridin-6-yl)phenyl-κN,N',C]platinum(II)} bis-(perchlorate).

Du Xiang-Dang XD Mo Juan J Li Xin-Sheng XS Pan Yu-Shan YS Zhang Su-Mei SM

Acta crystallographica. Section E, Structure reports online 20080809 Pt 9

The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenyl-phosphino)meth-yl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2'-bipyridine (pbpy) ligand in a square-planar geometry. The other Pt atom is coordinated by one N atom from the dppmp ligand, and one C atom and two N atoms from another pbpy ligand in a square-planar geome ...[more]

PMID: 21201601

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