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Catena-Poly[[[diaqua-cobalt(II)]bis-(?-1,3-di-4-pyridylpropane-?N:N')] bis-(perchlorate) bis-(1,3-di-4-pyridyl-propane) bis-(2-methyl-4-nitro-aniline)].

ABSTRACT: In the title compound, {[Co(C(13)H(14)N(2))(2)(H(2)O)(2)](ClO(4))(2)·2C(13)H(14)N(2)·2C(7)H(8)N(2)O(2)}(n), the Co(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms from four symmetry-related 1,3-di-4-pyridylpropane ligands and two O atoms from two water ligands in a slightly distorted octa-hedral coordination environment. The 1,3-di-4-pyridylpropane ligands are doubly bridging and connect the Co(II) ions into one-dimensional chains. The asymmetric unit also contains one uncoordinated 1,3-di-4-pyridylpropane mol-ecule, one 2-methyl-4-nitro-aniline mol-ecule and one perchlorate anion. In the crystal structure, inter-molecular O-H?N hydrogen bonds connect the one-dimensional chains into a two-dimensional network.

SUBMITTER: Fu Z

PROVIDER: S-EPMC2960494 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Diaqua-tetra-kis-(1,3-di-4-pyridylpropane-κN)-manganese(II) bis-(perchlorate) ses-qui-hydrate.

Project description:In the title complex, [Mn(C(13)H(14)N(2))(4)(H(2)O)(2)](ClO(4))(2)·1.5H(2)O, the Mn(II) ion is coordinated by four N atoms from four different 1,3-di-4-pyridyl-propane mol-ecules and two O atoms from two coordinated water mol-ecules, leading to a distorted MnN(4)O(2) octa-hedral geometry. Each 1,3-di-4-pyridyl-propane ligand displays a monodentate coordinating mode. In the crystal, there exist O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds. The perchlorate anions and the coordinated and lattice water mol-ecules play an important role in the formation of these hydrogen bonds. One of the two lattice water molecules shows half-occupancy.

| S-EPMC3246966 | biostudies-literature

Bis(benzoyl-acetonato)bis-(1,3-di-4-pyridyl-propane)manganese(II).

Project description:In the title compound, [Mn(C(10)H(9)O(2))(2)(C(13)H(14)N(2))(2)], the Mn(II) ion lies on a crystallographic inversion center and has a slightly distorted octa-hedral coordination environment. Weak π-π stacking inter-actions, with centroid-centroid distances of 3.862 (2) and 3.887 (5) Å, and significant C-H⋯π inter-actions help to stabilize the crystal structure. The atoms of the unique terminal 4-pyridine-propane group are disordered over two sites, the ratio of refined occpancies being 0.712 (7):0.288 (7).

| S-EPMC2969015 | biostudies-literature

catena-Poly[cadmium-?-[1,3-bis-(imidazol-1-yl)propane]-di-?-chlorido].

Project description:The title complex, [CdCl(2)(C(9)H(12)N(4))](n), is characterized by the formation of a zigzag chain structure parallel to [001]. In the chain, the Cd(2+) cation is coordinated by four bridging Cl(-) ligands in equatorial positions and two N atoms from symmetry-related and likewise bridging 1,3-bis-(imidazol-1-yl)propane ligands in axial positions, forming a distorted CdCl(4)N(2) octa-hedron.

| S-EPMC3379108 | biostudies-literature

catena-Poly[[bis-(p-toluene-sulfonato-κO)palladium(II)]bis-(μ-1,3-di-4-pyridylpropane-κN:N')].

Project description:In the title compound, [Pd(C(7)H(7)O(3)S)(2)(C(13)H(14)N(2))(2)](n), the metal ion, located on a twofold rotation axis, exhibits a slightly distorted octa-hedral coordination environment, with bond angles that deviate by at most 2.2° from an ideal geometry, completed by two O atoms from two deprotonated p-toluene-sulfonic acid ligands and four N atoms from four 1,3-di-4-pyridylpropane ligands. One of the sulfonate O atoms is disordered over two positions [ratio 0.70 (5):0.30 (5)].

| S-EPMC2969940 | biostudies-literature

catena-Poly[[bis-(4-methyl-benzene-thiol-ato)cadium(II)]-μ-1,3-di-4-pyridylpropane].

Project description:In the title compound, [Cd(C(7)H(7)S)(2)(C(13)H(14)N(2))](n), the unique Cd(II) ion, located on a twofold rotation axis, is coordinated by two S atoms and two N atoms in a slightly distorted tetra-hedral environment. Symmetry-related Cd(II) ions are linked via bridging 1,3-di-4-pyridylpropane ligands, forming a zig-zag chain-structure parallel to [001]. In the crystal structure, there are weak intra-chain π-π stacking inter-actions between benzene rings, with a centroid-centroid distance of 3.825 (7) Å, and pairs of chains are inter-digitated with respect to the 4-methyl-benzene-thiol-ate groups.

| S-EPMC2968951 | biostudies-literature

catena-Poly[[[diaqua-copper(II)]-bis-[?(2)-1,3-bis-(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate].

Project description:The title Cu(II) coordination polymer, {[Cu(C(7)H(10)N(6))(2)(H(2)O)(2)](NO(3))(2)·H(2)O}(n), was obtained by the reaction of equimolar Cu(NO(3))(2)·4H(2)O and 1,3-bis-(1,2,4-triazol-1-yl)propane (btp) in a water-methanol solvent. The Cu(II) atom is located on a centre of inversion and has an elongated octa-hedral coordination geometry formed by four N atoms from four symmetry-related btp ligands and two coordinated water mol-ecules. Adjacent Cu(II) atoms are connected by btp ligands, generating a double-stranded chain. The nitrate anion is disordered over two positions in a 0.828?(7):0.172?(2) ratio.

| S-EPMC2970232 | biostudies-literature

catena-Poly[[[bis-[2,2'-(propane-1,3-diyl-dithio)bis-(1,3,4-thia-diazole)-?N]copper(II)]-bis-[?-2,2'-(propane-1,3-diyldithio)bis-(1,3,4-thia-diazole)-?N:N]] bis-(perchlorate)].

Project description:In the title compound, {[Cu(C(7)H(8)N(4)S(4))(4)](ClO(4))(2)}(n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by six N atoms of three symmetry-related 2,2'-(propane-1,3-diyldithio)bis-(1,3,4-thia-diazole) (L) ligands in a slightly distorted octa-hedral geometry. The ligand L adopts two kinds of coordination modes in the crystal structure; one is a monodentate coordination mode and serves to complete the octa-hedral coordination of the Cu atom and the other is an N:N'-bidentate bridging mode in a trans configuration, bridging Cu atoms via translation symmetry along the b axis into a chain structure. The perchlorate ions serve as acceptors for inter-molecular C-H?O hydrogen bonds, which link the chains into a three-dimensional network.

| S-EPMC2968698 | biostudies-literature

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Project description:The Zn(II) ion in the title compound, [Zn(C(15)H(14)N(10))(H(2)O)(2)](ClO(4))(2), lies on a centre of symmetry. The distorted N(4)O(2) octa-hedral coordination environment around the Zn atom is composed of two 1,3-bis-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]propane ligands (L1) and two water mol-ecules, coordinated in trans positions. The ligand acts as a typical bidentate chelating ligand through one of its 2-pyridyl-2H-tetra-zole units, forming a five-membered Zn-N-C-C-N metallacycle with a small N-Zn-N bite angle [77.40 (8)°]. The other 2-pyridyl-2H-tetra-zole unit remains uncoordinated. The average Zn-N distance (2.156 Å) is somewhat longer than the distance between the Zn(II) center and the aqua ligand [2.108 (2) Å]. The coordinated pyrid-yl-tetra-zoyl rings are quasi-coplanar, making a dihedral angle of 1.9 (2)°, while the uncoordinated rings show a larger inter-planar angle of 21.3 (2)°. The flexible propane spacer displays a zigzag chain. Inter-molecular O-H⋯N and O-H⋯O inter-actions result in two-dimensional polymeric structures parallel to (100). Two C atoms of the spacer are disordered over two positions, with site occupancy factors of ca 0.85 and 0.15.

| S-EPMC2960969 | biostudies-literature

catena-Poly[[[diaqua-copper(II)]-bis-(?(2)-di-4-pyridyl disulfide-?N:N')] bis-(hydrogen phthalate) monohydrate].

Project description:The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water mol-ecules, two hydrogen phthalate anions and one uncoordinated water mol-ecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octa-hedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water mol-ecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water mol-ecules.

| S-EPMC2979707 | biostudies-literature

catena-Poly[[dichloridocobalt(II)]-μ-1,3-di-4-pyridylpropane-κN:N'].

Project description:In the title compound, [CoCl(2)(C(13)H(14)N(2))](n), 1,3-bis-(4-pyrid-yl)propane (bpp) ligands bridge four-coordinate Co atoms, generating an extended one-dimensional zigzag chain. Both the Co and two Cl atoms in the tetrahedral coordination polyhedron lie on a mirror plane, while the bbp ligand is bis-ected through the central C atom in the chain by a second mirror plane. There are some π-π stacking inter-ations in the crystal structure, with inter-planar distances of 3.449 Å, which are responsible for the supra-molecular assembly.

| S-EPMC2961947 | biostudies-literature

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