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5-Bromo-2,4,6-trimethyl-3-phenyl-sulfinyl-1-benzofuran.

ABSTRACT: The title compound, C(17)H(15)BrO(2)S, which was synthesized by the oxidation of 5-bromo-2,4,6-trimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid, features a trigonally-coordinated S atom. The phenyl ring is approximately perpendicular to the plane of the benzofuran fragment [dihedral angle 75.11?(7)°]. The crystal structure is stabilized by non-classical C-H?O and Br?Br inter-actions [3.7169?(6)?Å].

SUBMITTER: Choi HD

PROVIDER: S-EPMC2960548 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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5-Bromo-2,4,6-trimethyl-3-phenyl-sulfinyl-1-benzofuran.

Choi Hong Dae HD Seo Pil Ja PJ Son Byeng Wha BW Lee Uk U

Acta crystallographica. Section E, Structure reports online 20080823 Pt 9

The title compound, C(17)H(15)BrO(2)S, which was synthesized by the oxidation of 5-bromo-2,4,6-trimethyl-3-phenyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid, features a trigonally-coordinated S atom. The phenyl ring is approximately perpendicular to the plane of the benzofuran fragment [dihedral angle 75.11 (7)°]. The crystal structure is stabilized by non-classical C-H⋯O and Br⋯Br inter-actions [3.7169 (6) Å]. ...[more]

PMID: 21201801

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2,4,6-Trimethyl-3-phenyl-sulfinyl-1-benzofuran.

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