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Catena-Poly[[aqua-(ethyl anilinophospho-nato-?O)sodium(I)]-di-?-aqua].


ABSTRACT: In the title compound, [Na(C(8)H(11)NO(3)P)(H(2)O)(3)](n), the sodium cation is octa-hedrally coordinated by five water mol-ecules and one O-bonded ethyl anilinophospho-nate anion. Four of the water mol-ecules bridge to adjacent sodium ions, resulting in an infinite chain of edge-sharing NaO(6) polyhedra. A network of N-H?O and O-H?O hydrogen bonds helps to stabilize the crystal structure.

SUBMITTER: Fu Z 

PROVIDER: S-EPMC2960560 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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catena-Poly[[aqua-(ethyl anilinophospho-nato-κO)sodium(I)]-di-μ-aqua].

Fu Zhiyong Z   Bai Shuqiong S  

Acta crystallographica. Section E, Structure reports online 20080813 Pt 9


In the title compound, [Na(C(8)H(11)NO(3)P)(H(2)O)(3)](n), the sodium cation is octa-hedrally coordinated by five water mol-ecules and one O-bonded ethyl anilinophospho-nate anion. Four of the water mol-ecules bridge to adjacent sodium ions, resulting in an infinite chain of edge-sharing NaO(6) polyhedra. A network of N-H⋯O and O-H⋯O hydrogen bonds helps to stabilize the crystal structure. ...[more]

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