Unknown

Dataset Information

0

4,4',5,5'-Tetra-methyl-2,2'-[1,1'-(propane-1,3-diyldinitrilo)diethyl-idyne]diphenol.


ABSTRACT: The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intra-molecular O-H?N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38?(4)°. In the crystal structure, neighbouring mol-ecules are linked along the c axis by weak inter-molecular C-H?O hydrogen bonds and are further packed into columns along the b axis, forming sheets which are parallel to the bc plane.

SUBMITTER: Yeap CS 

PROVIDER: S-EPMC2960569 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

altmetric image

Publications

4,4',5,5'-Tetra-methyl-2,2'-[1,1'-(propane-1,3-diyldinitrilo)diethyl-idyne]diphenol.

Yeap Chin Sing CS   Kia Reza R   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20080830 Pt 9


The title Schiff base compound, C(23)H(30)N(2)O(2), has crystallographic twofold rotation symmetry. An intra-molecular O-H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The imino group is coplanar with the benzene ring. The two benzene rings are almost perpendicular to each other, making a dihedral angle of 87.38 (4)°. In the crystal structure, neighbouring mol-ecules are linked along the c axis by weak inter-molecular C-H⋯O hydrogen bonds and are further packed into c  ...[more]

Similar Datasets

| S-EPMC2969254 | biostudies-literature
| S-EPMC2960484 | biostudies-literature
| S-EPMC2961531 | biostudies-literature
| S-EPMC2983949 | biostudies-literature
| S-EPMC2967979 | biostudies-literature
| S-EPMC2961936 | biostudies-literature
| S-EPMC2969260 | biostudies-literature
| S-EPMC3008013 | biostudies-literature