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Low-temperature redetermination of aqua-chloridotriphenyl-tin(IV)-1,10-phenanthroline (1/1).

ABSTRACT: The crystal structure of the title compound, [Sn(C(6)H(5))(3)Cl(H(2)O)]·C(12)H(8)N(2), which was refined in the triclinic space group P [Fu, Gao, Ma & Zhang (2005 ?). Chin. J. Synth. Chem. 13, 55-57], has been redetermined in the monoclinic space group C2/c from low-temperature diffraction measurements. The Sn atom is five-coordinate in a trans-C(3)SnClO trigonal-bipyramidal geometry; the coordinated water mol-ecule forms a pair of hydrogen bonds to the nitro-gen heterocycle.

SUBMITTER: Ng SW

PROVIDER: S-EPMC2960574 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Low-temperature redetermination of aqua-chloridotriphenyl-tin(IV)-1,10-phenanthroline (1/1).

Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080806 Pt 9

The crystal structure of the title compound, [Sn(C(6)H(5))(3)Cl(H(2)O)]·C(12)H(8)N(2), which was refined in the triclinic space group P [Fu, Gao, Ma & Zhang (2005 ▶). Chin. J. Synth. Chem. 13, 55-57], has been redetermined in the monoclinic space group C2/c from low-temperature diffraction measurements. The Sn atom is five-coordinate in a trans-C(3)SnClO trigonal-bipyramidal geometry; the coordinated water mol-ecule forms a pair of hydrogen bonds to the nitro-gen heterocycle. ...[more]

PMID: 21201582

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