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2,2'-[1,1'-(Hexane-1,6-diyldioxy-dinitrilo)diethyl-idyne]diphenol.


ABSTRACT: The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-mol-ecule in the asymmetric unit. The mol-ecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the mol-ecule, the planar units are parallel, but extend in opposite directions from the hexa-methyl-ene bridge. There are intra-molecular O-H?N hydrogen bonds between the hydroxyl groups and the oxime N atoms. There are also weak inter-molecular C-H?O bonds that link each mol-ecule to two others, forming chains along the a axis.

SUBMITTER: Dong WK 

PROVIDER: S-EPMC2960586 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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2,2'-[1,1'-(Hexane-1,6-diyldioxy-dinitrilo)diethyl-idyne]diphenol.

Dong Wen-Kui WK   He Xue-Ni XN   Sun Yin-Xia YX   Xu Li L   Tong Jun-Feng JF  

Acta crystallographica. Section E, Structure reports online 20080809 Pt 9


The molecule of the title compound, C(22)H(28)N(2)O(2), lies across an inversion centre with one half-mol-ecule in the asymmetric unit. The mol-ecule adopts an E configuration with respect to the azomethine C=N bond and the imino group is coplanar with the aromatic ring. Within the mol-ecule, the planar units are parallel, but extend in opposite directions from the hexa-methyl-ene bridge. There are intra-molecular O-H⋯N hydrogen bonds between the hydroxyl groups and the oxime N atoms. There are  ...[more]

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