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{?-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}dimethano-ltrinitratonickel(II)lanthanum(III) methanol disolvate.

ABSTRACT: In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa-hedral geometry. The La(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-anti-prismatic environment. In the crystal structure, inter-molecular O-H-O hydrogen bonds connect complex mol-ecules and methanol solvent mol-ecules, forming a two-dimensional network.

SUBMITTER: Liu F

PROVIDER: S-EPMC2960610 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}dimethano-ltrinitratonickel(II)lanthanum(III) methanol disolvate.

Liu Fei F

Acta crystallographica. Section E, Structure reports online 20080830 Pt 9

In the title dinuclear complex, [NiLa(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, the Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two O atoms of two methanol ligands, forming a slightly distorted octa-hedral geometry. The La(III) ion is coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the Schiff base ligand, forming a distorted bicapped square-anti-prismatic environment. In the crystal structure, inter-mole ...[more]

PMID: 21201643

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{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}dimethano-ltrinitratonickel(II)europium(III) methanol disolvate.

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